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OwnerMichael Grun, Thomas Knauf +1inventors
InventorsMichael Grun, Thomas Knauf, Wilfried Braubach
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The coupled polymers according to the present invention based on conjugated dienes or on conjugated dienes and vinylaromatic compounds and that are modified with electrophilic groups, prepared by reacting living anionic polymers based on the aforementioned monomers with functional organic compounds containing at least three groups capable of reacting with the living polymers and at least one group in the molecule serving for the modification of the polymers, have very good processing properties as well as improved physical and dynamic properties, together with the advantage that the coupling agents used do not exhibit any toxic effect during the processing. The polymers according to the present invention are suitable for the production of all types of molded articles, in particular for the production of tires and tire structural parts, golf balls and technical rubber articles, as well as for the production of rubber-reinforced plastics such as ABS and HIPS plastics.
A modified coupled polymer comprising electrophilic groups based on conjugated dienes or both conjugated dienes and vinylaromatic compounds as well as polyfunctional compounds with at least three groups capable of coupling and at least one electrophilic group which modifies the couple polymer, in which the polymer has a molecular weight ratio (MW/Mn) of 1.0:2.1, a weight average molecular weight (MW) of ≧50,000, a glass transition temperature (Tg) of −100° to −10° C., an amount of vinyl groups in the coupled polymer ranging from 5 to 90% referred to the diene units present in the coupled polymer, and a crosslinking number (coupling number) of at least 2, and in which the proportion of electrophilic groups which modifies the coupled polymer, referred to the amount of the alkali metal-terminated polymer anions formed as intermediates in the production of the coupled polymer, is 3 to 33 mole %.
Process for the production of modified coupled polymer comprising electrophilic groups comprising the steps of polymerizing a conjugated diene or both a conjugated diene and an vinylaromatic compound in the presence of an inert organic solvent and in the presence of an organic alkali metal compound, reacting the alkali metal-terminated polymer anion that is formed during the polymerization step with a polyfunctional compound containing at least three groups capable of coupling and at least one electrophilic group which modifies the coupled polymer, wherein the molar ratio of polyfunctional compounds used to alkali metal-terminated polymer anions is 0.03 to 0.33:1.
A vulcanizate comprising a modified coupled polymer comprising electrophilic groups based on conjugated dienes or both conjugated dienes and vinylaromatic compounds as well as polyfunctional compounds with at least three groups capable of coupling and at least one electrophilic group which modifies the couple polymer, in which the polymer has a molecular weight ratio (MW/Mn) of 1.0:2.1, a weight average molecular weight (MW) of ≧50,000, a glass transition temperature (Tg) of −100° to −10° C., an amount of vinyl groups in the coupled polymer ranging from 5 to 90% referred to the diene units present in the coupled polymer, and a crosslinking number (coupling number) of at least 2, and in which the proportion of electrophilic groups which modifies the coupled polymer, referred to the amount of the alkali metal-terminated polymer anions formed as intermediates in the production of the coupled polymer, is 3 to 33 mole %.
A rubber molded article comprising a modified coupled polymer comprising electrophilic groups based on conjugated dienes or both conjugated dienes and vinylaromatic compounds as well as polyfunctional compounds with at least three groups capable of coupling and at least one electrophilic group which modifies the couple polymer, in which the polymer has a molecular weight ratio (MW/Mn) of 1.0:
Dependencies are inferred from the claim text.