US 2003/0069366 A1Published application

Urethane oligomers of heterotelechelic amine functional polyolefins

OwnerRobert J. Letchford, Thorsten Brockmann +3inventors

InventorsRobert J. Letchford, Thorsten Brockmann, John F. Engel, James A. Schwindeman, John L. Greak

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Abstract

The present invention provides urethane oligomers of α,functional heterotelechelic polymers, and in particular heterotelechelic polyolefins having at least one terminal hydroxyl functionality and one other terminal functional group which is different from the hydroxyl functionality, such as an amine functional group. The oligomers of the invention can exhibit toughness, chemical resistance and other desired properties. The oligomers can also exhibit improved flexibility and impact resistance, due to the incorporation of the polyolefinic backbone. Thus the oligomers can be used in a variety of applications, including without limitation coatings, sealants, adhesives, and composites (prepregs). The heterotelechelic polyolefin is advantageously prepared via anionic polymerization using lithium initiators, and in particular functionalized lithium initiators having a protected hydroxy functionality as known in the art. The resulting living chain end can be functionalized using an amine functionalized electrophile, in which typically the amine group is protected. Alternatively amine protected functionalized initiators can used and the resulting living polymer functionalized using a hydroxy functionalizing electrophile. Protecting groups, when present, are removed to liberate the desired functionalities.

Claims2

Dependent claims

A heterotelechelic polymer comprising

Q-R1Q wherein R1 is a polyolefin, at least one Q is a hydroxyl groups and the other Q is an amine groups or is
T(H)m-Z-Qn-C-y-W(H)k wherein C represents a hydrogenated or unsaturated block derived by anionic polymerization of one or more conjugated diene hydrocarbons, one or more alkenylsubstituted aromatic hydrocarbons, or mixtures thereof;
Y is a branched or straight chain hydrocarbon connecting group which contains 1-25 carbon atoms optionally substituted with aryl or substituted aryl containing lower alkyl, lower alkylthio, or lower dialkylamino groups;
Z is a branched or straight chain hydrocarbon connecting groups which contains 3-25 carbon atoms optionally substituted with aryl or substituted aryl containing lower alkyl, lower alkylthio, or lower dialkylamino groups;
Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of one or more conjugated diene hydrocarbons, one or more alkenylsubstituted aromatic hydrocarbons, or mixtures thereof;
n is a number from 0 to 5;
T and W are each independently selected from oxygen and nitrogen, with the proviso that at least one of T or W is oxygen and the other of T or W is nitrogen;
and k and m are 1 when T or W is oxygen, and 2 when T or W is nitrogen prepared by anionic polymerization using a functionalized lithium initiator having protected hydroxy functionality.

5 more elements

Dependencies are inferred from the claim text.

Facts

Application: 10/245,451Filed 17 Sep 2002
Priority: 17 Sep 2001
Published: 10 Apr 2003
Term ends: Not estimatedThe source records don’t support an estimate.

Classification4 codes

C08L 19/006
Compositions of rubbers not provided for in groups C08L7/00 - C08L17/00: rubber characterised by functional groups, e.g. telechelic diene polymers
C08F 8/32
Introducing nitrogen atoms or nitrogen-containing groups: by reaction with amines
C08L
Compositions of macromolecular compounds
C08F
Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds