Smudge resistant nanocomposite hardcoats and methods for making same
Assignee3M Innovative Properties Company
InventorsDavid S. Arney, Judith M. Invie, Alexander B. Doust
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Abstract
Nanocomposite hardcoats having smudge and abrasion resistant properties are disclosed. Latent reactive nanoparticles are contained within a binder phase to form a nanocomposite. When deprotected and treated with a reactive fluorochemical, nanoparticles present at the surface of the nanocomposite become permanently modified and impart smudge resistance. The nanocomposite hardcoats may optionally be supported on a primary substrate.
Claims67
A method for preparing a smudge and abrasion resistant article comprising the steps of:
- a) contacting a plurality of nanoparticles with a latent coupling agent to form latent reactive nanoparticles;
- b) intimately mixing the latent reactive nanoparticles with a binder precursor;
- c) curing the binder precursor to form a nanocomposite having an exposed first surface comprising latent reactive nanoparticles;
- d) deprotecting a plurality of latent reactive nanoparticles to form reactive nanoparticles at the first surface of the nanocomposite;
- and
- e) contacting a reactive fluorochemical with the first surface of the nanocomposite such that fluorinated organic groups are covalently bonded to a plurality of the reactive nanoparticles present at the first surface of the nanocomposite.
A nanocomposite article having a first major surface and an interior portion comprising a binder and nanoparticles wherein the first major surface comprises nanoparticles having covalently bonded fluorinated organic groups, and wherein the interior portion comprises latent reactive nanoparticles.
A nanocomposite article having a first major surface and an interior portion comprising a binder and nanoparticles wherein the first major surface comprises reactive nanoparticles, and wherein the interior portion comprises latent reactive nanoparticles.
Dependencies are inferred from the claim text.