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US 2002/0176875 A9Published application
Cosmetic compositions comprising an amphoteric starch and a cationic conditioner, and uses thereof
OwnerVeronique Douin, Laurent Chesneau +1inventors
InventorsVeronique Douin, Laurent Chesneau, Sandrine Decoster
Life of this patent
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Abstract
Cosmetic compositions comprising, in a cosmetically acceptable medium, at least one specific amphoteric starch and at least one cationic conditioner. This combination can provide cosmetic properties such as smoothness, lightness, and suppleness without certain cosmetic effects considered undesirable. These compositions can be used for washing and/or conditioning keratin materials such as the hair or the skin.
Claims66
A cosmetic composition, comprising in a cosmetically acceptable medium:
- a) at least one amphoteric starch chosen from the compounds of formulae (I) to (IV):
- 19
- wherein:
- St-O is a starch moiety,
- R, which may be identical or different, are each chosen from a hydrogen atom and a methyl group,
- R′, which may be identical or different, are each chosen from a hydrogen atom, a methyl group, and a —COOH group,
- n is chosen from integers ranging from 2 to 3,
- M, which may be identical or different, are each chosen from a hydrogen atom, an alkali metal, an alkaline-earth metal, NH4, quaternary ammonium compounds, and organic amines, and
- R″, which may be identical or different, are each chosen from a hydrogen atom, and alkyl groups comprising from 1 to 18 carbon atoms;
- and
- b) at least one cationic conditioner chosen from cationic silicones, quaternary ammonium salt surfactants, cyclopolymers of alkyldiallylamine, cyclopolymers of dialkyldiallylammonium, and polyquaternary ammonium polymers chosen from:
- (1) diquaternary ammonium polymers comprising repeating units of formula (IV):
- 20
- wherein:
- R13, R14, R15 and R16, which may be identical or different, are each chosen from aliphatic groups comprising from 1 to 20 carbon atoms, alicyclic groups comprising from 1 to 20 carbon atoms, arylaliphatic groups comprising from 1 to 20 carbon atoms, lower hydroxyalkylaliphatic groups, and, additionally,
- at least two of said R13, R14, R15 and R16, with the nitrogen atoms to which they are attached, form at least one heterocycle optionally comprising an additional heteroatom other than nitrogen, and, additionally,
- R13, R14, R15 and R16, which may be identical or different, are each chosen from linear and branched C1-C6 alkyl groups substituted with at least one group chosen from nitrile groups, ester groups, acyl groups, amide groups and groups chosen from groups of formulae —CO—O—R17-D and —CO—NH—R17-D wherein R17 is chosen from alkylene groups and D is chosen from quaternary ammonium groups;
- A1 and B1, which may be identical or different, are each chosen from polymethylene groups comprising from 2 to 20 carbon atoms, chosen from linear and branched, saturated and unsaturated polymethylene groups wherein said polymethylene groups may optionally comprise, optionally linked to and optionally intercalated in the main chain, at least one entity chosen from aromatic rings, oxygen atoms, sulfur atoms, sulfoxide groups, sulfone groups, disulfide groups, amino groups, alkylamino groups, hydroxyl groups, quaternary ammonium groups, ureido groups, amide groups and ester groups;
- X− is an anion chosen from anions derived from inorganic acids and anions derived from organic acids;
- and
- A1, R13 and R15 may optionally form, together with the two nitrogen cations to which they are attached, at least one piperazine ring;
- with the proviso that if A1 is chosen from linear and branched, saturated and unsaturated alkylene groups and linear and branched, saturated and unsaturated hydroxyalkylene groups, B1 may also be chosen from groups of formula:
- (CH2)n—CO—D-OC—(CH2)n—
- wherein D is chosen from:
- a) glycol residues of formula:
- —O-Z-O—, wherein Z is chosen from linear and branched hydrocarbon groups and groups chosen from groups of formulae:
- —(CH2—CH2—O)x—CH2—CH2—;
- and—[CH2—CH(CH3)—O]y—CH2—CH(CH3)—
- wherein x and y, which may be identical or different, are each chosen from integers ranging from 1 to 4 (in which case x and y represent a defined and unique degree of polymerization) and any number ranging from 1 to 4 (in which case x and y represent an average degree of polymerization);
- b) bis-secondary diamine residues such as piperazine derivatives;
- c) bis-primary diamine residues chosen from residues of formula:
- —NH—Y—NH—, wherein Y is chosen from linear and branched hydrocarbon groups and residues of formula —CH2—CH2—S—S—CH2—CH2—;
- and
- d) ureylene groups of formula:
- —NH—CO—NH—;
- and
- (2) polyquaternary ammonium polymers comprising at least one unit of formula (VII):
- 21
- wherein:
- R18, R19 R20 and R21, which may be identical or different, are each chosen from a hydrogen atom, a methyl group, an ethyl group, a propyl group, a β-hydroxyethyl group, a β-hydroxypropyl group, and a —CH2CH2(OCH2CH2)pOH group, wherein p is an integer ranging from 0 to 6;
- with the proviso that R18, R19, R20 and R21 are all not simultaneously hydrogen atoms;
- r and s, which may be identical or different, are each chosen from integers ranging from 1 to 6;
- q is an integer ranging from 1 to 34;
- X− is chosen from anions of inorganic and organic acids,
- D is chosen from direct bonds and —(CH2)t—CO— groups wherein t is 4 or 7;
- and
- A is chosen from dihalide groups and a group of formula —CH2—CH2—O—CH2—CH2—.
44 more elements
A shampoo, a rinse-out conditioner, a leave-in conditioner, a hair permanent-waving composition, a hair straightening composition, a hair dyeing composition, a hair bleaching composition, a rinse-out composition to be applied between steps of a permanent-waving operation, a rinse-out composition to be applied between steps of a hair-straightening operation, comprising, in a cosmetically acceptable medium:
- a) at least one amphoteric starch chosen from the compounds of formulae (I) to (IV):
- 36
- wherein:
- St-O is a starch moiety,
- R, which may be identical or different, are each chosen from a hydrogen atom and a methyl group,
- R′, which may be identical or different, are each chosen from a hydrogen atom, a methyl group, and a —COOH group,
- n is chosen from integers ranging from 2 to 3,
- M, which may be identical or different, are each chosen from a hydrogen atom, an alkali metal, an alkaline-earth metal, NH4, quaternary ammonium compounds, and organic amines, and
- R″, which may be identical or different, are each chosen from a hydrogen atom, and alkyl groups comprising from 1 to 18 carbon atoms;
- and
- b) at least one cationic conditioner chosen from cationic silicones, quaternary ammonium salt surfactants, cyclopolymers of alkyldiallylamine, cyclopolymers of dialkyldiallylammonium, and polyquaternary ammonium polymers chosen from:
- (1) diquaternary ammonium polymers comprising repeating units of formula (IV):
- 37
- wherein:
- R13, R14, R15 and R16, which may be identical or different, are each chosen from aliphatic groups comprising from 1 to 20 carbon atoms, alicyclic groups comprising from 1 to 20 carbon atoms, arylaliphatic groups comprising from 1 to 20 carbon atoms, lower hydroxyalkylaliphatic groups, and, additionally,
- at least two of said R13, R14, R15 and R16, with the nitrogen atoms to which they are attached, form at least one heterocycle optionally comprising an additional heteroatom other than nitrogen, and, additionally,
- R13, R14, R15 and R16, which may be identical or different, are each chosen from linear and branched C1-C6 alkyl groups substituted with at least one group chosen from nitrile groups, ester groups, acyl groups, amide groups and groups chosen from groups of formulae —CO—O—R17-D and —CO—NH—R17-D wherein R17 is chosen from alkylene groups and D is chosen from quaternary ammonium groups;
- A1 and B1, which may be identical or different, are each chosen from polymethylene groups comprising from 2 to 20 carbon atoms, chosen from linear and branched, saturated and unsaturated polymethylene groups wherein said polymethylene groups may optionally comprise, optionally linked to and optionally intercalated in the main chain, at least one entity chosen from aromatic rings, oxygen atoms, sulfur atoms, sulfoxide groups, sulfone groups, disulfide groups, amino groups, alkylamino groups, hydroxyl groups, quaternary ammonium groups, ureido groups, amide groups and ester groups;
- X− is an anion chosen from anions derived from inorganic acids and anions derived from organic acids;
- and
- A1, R13 and R15 may optionally form, together with the two nitrogen cations to which they are attached, at least one piperazine ring;
- with the proviso that if A1 is chosen from linear and branched, saturated and unsaturated alkylene groups and linear and branched, saturated and unsaturated hydroxyalkylene groups, B1 may also be chosen from groups of formula:
- (CH2)n—CO—D-O-C—(CH2)n—
- wherein D is chosen from:
- a) glycol residues of formula:
- —O-Z-O—, wherein Z is chosen from linear and branched hydrocarbon groups and groups chosen from groups of formulae:
- —(CH2—CH2—O)x—CH2—CH2—;
- and—[CH2—CH(CH3)—O]y—CH2—CH(CH3)—
- wherein x and y, which may be identical or different, are each chosen from integers ranging from 1 to 4 (in which case x and y represent a defined and unique degree of polymerization) and any number ranging from 1 to 4 (in which case x and y represent an average degree of polymerization);
- b) bis-secondary diamine residues such as piperazine derivatives;
- c) bis-primary diamine residues chosen from residues of formula:
- —NH—Y—NH—, wherein Y is chosen from linear and branched hydrocarbon groups and residues of formula —CH2—CH2—S—S—CH2—CH2—;
- and
- d) ureylene groups of formula:
- —NH—CO—NH—;
- and
- (2) polyquaternary ammonium polymers comprising at least one unit of formula (VII):
- 38
- wherein:
- R18, R19, R20 and R21, which may be identical or different, are each chosen from a hydrogen atom, a methyl group, an ethyl group, a propyl group, a β-hydroxyethyl group, a β-hydroxypropyl group, and a —CH2CH2(OCH2CH2)pOH group, wherein p is an integer ranging from 0 to 6;
- with the proviso that R18, R19, R20 and R21 are all not simultaneously hydrogen atoms;
- r and s, which may be identical or different, are each chosen from integers ranging from 1 to 6;
- q is an integer ranging from 1 to 34;
- X− is chosen from anions of inorganic and organic acids,
- D is chosen from direct bonds and —(CH2)t—CO— groups wherein t is 4 or 7;
- and
- A is chosen from dihalide groups and a group of formula —CH2—CH2—O—CH2—CH2—.
44 more elements
A shower gel, a bubble bath or a make-up-removing product comprising, in a cosmetically acceptable medium:
- a) at least one amphoteric starch chosen from the compounds of formulae (I) to (IV):
- 39
- wherein:
- St-O is a starch moiety,
- R, which may be identical or different, are each chosen from a hydrogen atom and a methyl group,
- R′, which may be identical or different, are each chosen from a hydrogen atom, a methyl group, and a —COOH group,
- n is chosen from integers ranging from 2 to 3,
- M, which may be identical or different, are each chosen from a hydrogen atom, an alkali metal, an alkaline-earth metal, NH4, quaternary ammonium compounds, and organic amines, and
- R″, which may be identical or different, are each chosen from a hydrogen atom, and alkyl groups comprising from 1 to 18 carbon atoms;
- and
- b) at least one cationic conditioner chosen from cationic silicones, quaternary ammonium salt surfactants, cyclopolymers of alkyldiallylamine, cyclopolymers of dialkyldiallylammonium, and polyquaternary ammonium polymers chosen from:
- (1) diquaternary ammonium polymers comprising repeating units of formula (IV):
- 40
- wherein:
- R13, R14, R15, and R16, which may be identical or different, are each chosen from aliphatic groups comprising from 1 to 20 carbon atoms, alicyclic groups comprising from 1 to 20 carbon atoms, arylaliphatic groups comprising from 1 to 20 carbon atoms, lower hydroxyalkylaliphatic groups, and, additionally,
- at least two of said R13, R14, R15 and R16, with the nitrogen atoms to which they are attached, form at least one heterocycle optionally comprising an additional heteroatom other than nitrogen, and, additionally,
- R13, R14, R,15 and R16, which may be identical or different, are each chosen from linear and branched C1-C6 alkyl groups substituted with at least one group chosen from nitrile groups, ester groups, acyl groups, amide groups and groups chosen from groups of formulae —CO—O—R17-D and —CO—NH—R17-D wherein R17 is chosen from alkylene groups and D is chosen from quaternary ammonium groups;
- A1 and B1, which may be identical or different, are each chosen from polymethylene groups comprising from 2 to 20 carbon atoms, chosen from linear and branched, saturated and unsaturated polymethylene groups wherein said polymethylene groups may optionally comprise, optionally linked to and optionally intercalated in the main chain, at least one entity chosen from aromatic rings, oxygen atoms, sulfur atoms, sulfoxide groups, sulfone groups, disulfide groups, amino groups, alkylamino groups, hydroxyl groups, quaternary ammonium groups, ureido groups, amide groups and ester groups;
- X− is an anion chosen from anions derived from inorganic acids and anions derived from organic acids;
- and
- A1, R13 and R15 may optionally form, together with the two nitrogen cations to which they are attached, at least one piperazine ring;
- with the proviso that if A1 is chosen from linear and branched, saturated and unsaturated alkylene groups and linear and branched, saturated and unsaturated hydroxyalkylene groups, B1 may also be chosen from groups of formula:
- (CH2)n—CO—D-OC—(CH2)n—
- wherein D is chosen from:
- a) glycol residues of formula:
- —O-Z-O—, wherein Z is chosen from linear and branched hydrocarbon groups and groups chosen from groups of formulae:
- —(CH2—CH2—O)x—CH2—CH2—;
- and—[CH2—CH(CH3)—O]y—CH2—CH(CH3)—
- wherein x and y, which may be identical or different, are each chosen from integers ranging from 1 to 4 (in which case x and y represent a defined and unique degree of polymerization) and any number ranging from 1 to 4 (in which case x and y represent an average degree of polymerization);
- b) bis-secondary diamine residues such as piperazine derivatives;
- c) bis-primary diamine residues chosen from residues of formula:
- —NH—Y—NH—, wherein Y is chosen from linear and branched hydrocarbon groups and residues of formula —CH2—CH2—S—S—CH2—CH2—;
- and
- d) ureylene groups of formula:
- —NH—CO—NH—;
- and
- (2) polyquaternary ammonium polymers comprising at least one unit of formula (VII):
- 41
- wherein:
- R18, R19, R20 and R21, which may be identical or different, are each chosen from a hydrogen atom, a methyl group, an ethyl group, a propyl group, a β-hydroxyethyl group, a β-hydroxypropyl group, and a —CH2CH2(OCH2CH2)pOH group, wherein p is an integer ranging from 0 to 6;
- with the proviso that R18, R19, R20 and R21 are all not simultaneously hydrogen atoms;
- r and s, which may be identical or different, are each chosen from integers ranging from 1 to 6;
- q is an integer ranging from 1 to 34;
- X− is chosen from anions of inorganic and organic acids,
- D is chosen from direct bonds and —(CH2)t—CO— groups wherein t is 4 or 7;
- and
- A is chosen from dihalide groups and a group of formula —CH2—CH2—O—CH2—CH2—.
44 more elements
A process for treating a keratin material comprising applying to said keratin material an amount of a composition effective to treat said keratin materials, said composition comprising, in a cosmetically acceptable medium:
- a) at least one amphoteric starch chosen from the compounds of formulae (I) to (IV):
- 42
- wherein:
- St-O is a starch moiety,
- R, which may be identical or different, are each chosen from a hydrogen atom and a methyl group,
- R′, which may be identical or different, are each chosen from a hydrogen atom, a methyl group, and a —COOH group,
- n is chosen from integers ranging from 2 to 3,
- M, which may be identical or different, are each chosen from a hydrogen atom, an alkali metal, an alkaline-earth metal, NH4, quaternary ammonium compounds, and organic amines, and
- R″, which may be identical or different, are each chosen from a hydrogen atom, and alkyl groups comprising from 1 to 18 carbon atoms;
- and
- b) at least one cationic conditioner chosen from cationic silicones, quaternary ammonium salt surfactants, cyclopolymers of alkyldiallylamine, cyclopolymers of dialkyldiallylammonium, and polyquaternary ammonium polymers chosen from:
- (1) diquaternary ammonium polymers comprising repeating units of formula (IV):
- 43
- wherein:
- R13, R14, R15 and R16, which may be identical or different, are each chosen from aliphatic groups comprising from 1 to 20 carbon atoms, alicyclic groups comprising from 1 to 20 carbon atoms, arylaliphatic groups comprising from 1 to 20 carbon atoms, lower hydroxyalkylaliphatic groups, and, additionally,
- at least two of said R13, R14, R15 and R16, with the nitrogen atoms to which they are attached, form at least one heterocycle optionally comprising an additional heteroatom other than nitrogen, and, additionally,
- R13, R14, R15 and R16, which may be identical or different, are each chosen from linear and branched C1-C6 alkyl groups substituted with at least one group chosen from nitrile groups, ester groups, acyl groups, amide groups and groups chosen from groups of formulae —CO—O—R17-D and —CO—NH—R17-D wherein R17 is chosen from alkylene groups and D is chosen from quaternary ammonium groups;
- A1 and B1, which may be identical or different, are each chosen from polymethylene groups comprising from 2 to 20 carbon atoms, chosen from linear and branched, saturated and unsaturated polymethylene groups wherein said polymethylene groups may optionally comprise, optionally linked to and optionally intercalated in the main chain, at least one entity chosen from aromatic rings, oxygen atoms, sulfur atoms, sulfoxide groups, sulfone groups, disulfide groups, amino groups, alkylamino groups, hydroxyl groups, quaternary ammonium groups, ureido groups, amide groups and ester groups;
- X− X is an anion chosen from anions derived from inorganic acids and anions derived from organic acids;
- and
- A1, R13 and R15 may optionally form, together with the two nitrogen cations to which they are attached, at least one piperazine ring;
- with the proviso that if A1 is chosen from linear and branched, saturated and unsaturated alkylene groups and linear and branched, saturated and unsaturated hydroxyalkylene groups, B1 may also be chosen from groups of formula:
- (CH2)n—CO—D-OC—(CH2)n—
- wherein D is chosen from:
- a) glycol residues of formula:
- —O-Z-O—, wherein Z is chosen from linear and branched hydrocarbon groups and groups chosen from groups of formulae:
- —(CH2—CH2—O)x—CH2—CH2—;
- and—[CH2—CH(CH3)—O]y—CH2—CH(CH3)—
- wherein x and y, which may be identical or different, are each chosen from integers ranging from 1 to 4 (in which case x and y represent a defined and unique degree of polymerization) and any number ranging from 1 to 4 (in which case x and y represent an average degree of polymerization);
- b) bis-secondary diamine residues such as piperazine derivatives;
- c) bis-primary diamine residues chosen from residues of formula:
- —NH—Y—NH—, wherein Y is chosen from linear and branched hydrocarbon groups and residues of formula —CH2—CH2—S—S—CH2—CH2—;
- and
- d) ureylene groups of formula:
- —NH—CO—NH—;
- and
- (2) polyquaternary ammonium polymers comprising at least one unit of formula (VII):
- 44
- wherein:
- R18, R19, R20 and R21, which may be identical or different, are each chosen from a hydrogen atom, a methyl group, an ethyl group, a propyl group, a β-hydroxyethyl group, a β-hydroxypropyl group, and a —CH2CH2(OCH2CH2)pOH group, wherein p is an integer ranging from 0 to 6;
- with the proviso that R18, R19, R20 and R21 are all not simultaneously hydrogen atoms;
- r and s, which may be identical or different, are each chosen from integers ranging from 1 to 6;
- q is an integer ranging from 1 to 34;
- X− is chosen from anions of inorganic and organic acids,
- D is chosen from direct bonds and —(CH2)t—CO— groups wherein t is 4 or 7;
- and
- A is chosen from dihalide groups and a group of formula —CH2—CH2—O—CH2—CH2—.
44 more elements
A process for washing and conditioning a keratin material comprising applying to said keratin material an effective amount of a composition to wash and condition said keratin material;
- and rinsing said keratin material with water, said composition comprising, in a cosmetically acceptable medium:
- a) at least one amphoteric starch chosen from the compounds of formulae (I) to (IV):
- 45
- wherein:
- St-O is a starch moiety,
- R, which may be identical or different, are each chosen from a hydrogen atom and a methyl group,
- R′, which may be identical or different, are each chosen from a hydrogen atom, a methyl group, and a —COOH group,
- n is chosen from integers ranging from 2 to 3,
- M, which may be identical or different, are each chosen from a hydrogen atom, an alkali metal, an alkaline-earth metal, NH4, quaternary ammonium compounds, and organic amines, and
- R″, which may be identical or different, are each chosen from a hydrogen atom, and alkyl groups comprising from 1 to 18 carbon atoms;
- and
- b) at least one cationic conditioner chosen from cationic silicones, quaternary ammonium salt surfactants, cyclopolymers of alkyldiallylamine, cyclopolymers of dialkyldiallylammonium, and polyquaternary ammonium polymers chosen from:
- (1) diquaternary ammonium polymers comprising repeating units of formula (IV):
- 46
- wherein:
- R13, R14, R15 and R16, which may be identical or different, are each chosen from aliphatic groups comprising from 1 to 20 carbon atoms, alicyclic groups comprising from 1 to 20 carbon atoms, arylaliphatic groups comprising from 1 to 20 carbon atoms, lower hydroxyalkylaliphatic groups, and, additionally,
- at least two of said R13, R14, R15 and R16, with the nitrogen atoms to which they are attached, form at least one heterocycle optionally comprising an additional heteroatom other than nitrogen, and, additionally,
- R13, R14, R15 and R16, which may be identical or different, are each chosen from linear and branched C1-C6 alkyl groups substituted with at least one group chosen from nitrile groups, ester groups, acyl groups, amide groups and groups chosen from groups of formulae —CO—O—R17-D and —CO—NH—R17-D wherein R17 is chosen from alkylene groups and D is chosen from quaternary ammonium groups;
- A1 and B1, which may be identical or different, are each chosen from polymethylene groups comprising from 2 to 20 carbon atoms, chosen from linear and branched, saturated and unsaturated polymethylene groups wherein said polymethylene groups may optionally comprise, optionally linked to and optionally intercalated in the main chain, at least one entity chosen from aromatic rings, oxygen atoms, sulfur atoms, sulfoxide groups, sulfone groups, disulfide groups, amino groups, alkylamino groups, hydroxyl groups, quaternary ammonium groups, ureido groups, amide groups and ester groups;
- X− is an anion chosen from anions derived from inorganic acids and anions derived from organic acids;
- and
- A1, R13 and R15 may optionally form, together with the two nitrogen cations to which they are attached, at least one piperazine ring;
- with the proviso that if A1 is chosen from linear and branched, saturated and unsaturated alkylene groups and linear and branched, saturated and unsaturated hydroxyalkylene groups, B1 may also be chosen from groups of formula:
- (CH2)n—CO-D-OC—(CH2)n—
- wherein D is chosen from:
- a) glycol residues of formula:
- —O-Z-O—, wherein Z is chosen from linear and branched hydrocarbon groups and groups chosen from groups of formulae:
- —(CH2—CH2—O)x—CH2—CH2—;
- and—[CH2—CH(CH3)—O]y—CH2—CH(CH3)—
- wherein x and y, which may be identical or different, are each chosen from integers ranging from 1 to 4 (in which case x and y represent a defined and unique degree of polymerization) and any number ranging from 1 to 4 (in which case x and y represent an average degree of polymerization);
- b) bis-secondary diamine residues such as piperazine derivatives;
- c) bis-primary diamine residues chosen from residues of formula:
- —NH—Y—NH—, wherein Y is chosen from linear and branched hydrocarbon groups and residues of formula —CH2—CH2—S—S—CH2—CH2—;
- and
- d) ureylene groups of formula:
- —NH—CO—NH—;
- and
- (2) polyquaternary ammonium polymers comprising at least one unit of formula (VII):
- 47
- wherein:
- R18, R19, R20 and R21, which may be identical or different, are each chosen from a hydrogen atom, a methyl group, an ethyl group, a propyl group, a β-hydroxyethyl group, a β-hydroxypropyl group, and a —CH2CH2(OCH2CH2)pOH group, wherein p is an integer ranging from 0 to 6;
- with the proviso that R18, R19, R20 and R21 are all not simultaneously hydrogen atoms;
- r and s, which may be identical or different, are each chosen from integers ranging from 1 to 6;
- q is an integer ranging from 1 to 34;
- X− is chosen from anions of inorganic and organic acids,
- D is chosen from direct bonds and —(CH2)t—CO— groups wherein t is 4 or 7;
- and
- A is chosen from dihalide groups and a group of formula —CH2—CH2—O—CH2—CH2—.
45 more elements
Dependencies are inferred from the claim text.