Polyolefin production
AssigneeFina Research, S.A.
InventorsAbbas Razavi, Olivier Miserque
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AssigneeFina Research, S.A.
InventorsAbbas Razavi, Olivier Miserque
Estimating the term…
A metallocene compound having the general formula: CpAXMQ1Q2Cp′A′X′M′Q1′Q2′ wherein Cp and Cp′ are each independently a substituted or unsubstituted cyclopentadienyl moiety; M and M′ are each independently a metal chosen from Group IV B transition metals and vanadium, and coordinate to Cp and Cp′ respectively; X and X′ are each independently a substituted or unsubstituted Group VA or VIA heteroatom and coordinate to M and M″ respectively; A and A′ are bridging groups between Cp and X and between Cp′ and X′ respectively and are independently chosen from —SiR′2—O—SiR′2—, —SinR′m—, —CnR′m— and —CR′2—SiR′2—CR′2—SiR′2—, in which each R′ is independently H or hydrocarbyl having 1 to 20 carbon atoms, n is an integer in the range 1 to 4 and m=2n; each Q1, Q2 and Q1′ and Q2′ is independently a coordinating group which is hydrogen, halogen or hydrocarbyl having 1 to 20 carbon atoms and each of Q1 and Q1′ is coordinated to both M and M′.
A metallocene compound having the general formula:
A metallocene compound according to any one of the preceding claims, wherein the metal is Zr.
A metallocene compound according to any one of the preceding claims, wherein the heteroatom is nitrogen, phosphorus, oxygen or sulphur and is substituted with H, hydrocarbyl having 1 to 20 carbon atoms or silyl.
A metallocene compound according to any one of the preceding claims, wherein each A and A′ is SiR′2.
A metallocene compound according to any one of the preceding claims, whose active site has local C2 symmetry.
A metallocene compound according to any one of the preceding claims, which has a dimeric structure.
A metallocene compound comprising (t-butylamido)(2-methyl-4,5-benzoinden-1-yl)-1,1-dimethyl silane zirconium chloride or (t-butylamido) (2-methyl-4,5-benzoinden-1-yl)-1,1-dimethyl silane titanium chloride.
Use of a metallocene compound according to any one of the preceding claims, as a catalyst component for the production of a polyolefin.
Use of a catalyst comprising a metallocene compound for the production of isotactic polypropylene, wherein the metallocene compound has the general formula CpAXMQ2, in which Cp is a cyclopentadienyl moiety substituted so that when in use isotactic polypropylene is produced;
Dependencies are inferred from the claim text.