Shaped article of polyamide resin and production thereof
AssigneeMitsubishi Gas Chemical Company, Inc.
InventorsKazunobu Sato, Koji Yamamoto, Kazunobu Maruo, Satoshi Okada
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AssigneeMitsubishi Gas Chemical Company, Inc.
InventorsKazunobu Sato, Koji Yamamoto, Kazunobu Maruo, Satoshi Okada
Estimating the term…
The polyamide resin shaped article of the present invention is produced by preliminarily melt-kneading a m-xylylene-containing polyamide resin and a layered silicate subjected to a swelling treatment to prepare a resin composition containing the layered silicate in high concentration, melt-kneading the resin composition with another portion of m-xylylene-containing polyamide resin, and then formed into the shaped article. Since the amount of the m-xylylene-containing polyamide resin exposed to the heat history twice in the melt-kneading steps is minimized, the gel formation due to the thermal degradation can be reduced and the lowering of the relative viscosity due to the decrease of the molecular weight caused by the thermal degradation of the m-xylylene-containing polyamide resin is prevented.
A polyamide resin shaped article comprising (A) 92 to 99.7 mass % of a polyamide resin produced by polycondensation of a diamine component containing 70 mol % or more of m-xylylenediamine and a dicarboxylic acid component containing 70 mol % or more of a straight-chain, aliphatic α, ω-dicarboxylic acid having 4 to 12 carbon atoms, and (B) 8 to 0.3 mass % of a silicate prepared by treating a layered silicate with an organic swelling agent with the proviso that the mass percentages are based on a sum of the polyamide resin A and the silicate B, wherein the polyamide resin shaped article is produced by:
A method for producing a polyamide resin shaped article comprising (A) 92 to 99.7 mass % of a polyamide resin produced by polycondensation of a diamine component containing 70 mol % or more of m-xylylenediamine and a dicarboxylic acid component containing 70 mol % or more of a straight-chain, aliphatic α, ω-dicarboxylic acid having 4 to 12 carbon atoms, and (B) 8 to 0.3 mass % of a silicate prepared by treating a layered silicate with an organic swelling agent with the proviso that the mass percentages are based on a sum of the polyamide resin A and the silicate B, the method comprising:
Dependencies are inferred from the claim text.