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US 2001/0044507 A1Published application
Ethylene polymers
AssigneePhillips Petroleum Company
InventorsElizabeth A. Benham, Max P. McDaniel
Life of this patent
Estimating the term…
Abstract
A process comprising polymerizing ethylene with at least one olefin to produce a polymer, and said polymer are provided.
Claims21
A process comprising polymerizing ethylene with at least one olefin to produce a polymer,
- wherein said polymerizing is conducted in a polymerization zone,
- where said polymerization zone is essentially free of cocatalyst, and
- wherein said polymerizing is conducted using a catalyst,
- where said catalyst comprises chromium oxide on a support, and
- where the amount of said chromium on said support is from about 0.01 to 5 weight percent, and
- where said support comprises silica, and
- where said support is essentially free of titania, alumina and, phosphates, and
- where said support has a surface area from about 200 to about 550 square meters per gram, and
- where said support has a pore volume from about 0.7 to about 2.5 cubic centimeters per gram, and
- where said catalyst has been activated at a temperature in the range of about 600° C. to about 900° C. by using a oxidizing ambient, and
- where said catalyst after being activated is then reduced at a temperature in the range of about 200° C. to about 550° C. by using a reducing ambient, and
- wherein said polymerizing is conducted in the presence of hydrogen, and
- wherein the majority of said olefin is produced by said catalyst, during said polymerizing.
10 more elements
A polymer comprising the following properties a density from 0.95 to 0.955, a melt index from 0.2 to 0.6 g/10 min., a high load melt index from 20 to 70 g/10 min., and a heterogeneity index from 10 to 16, a shear ratio from 65 to 100, and a Bottle ESCR 100 percent higher than a comparison resin.
Dependencies are inferred from the claim text.