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US 2001/0041373 A1Published application
Thin film ferroelectric capacitors having improved memory retention through the use of essentially smooth bottom electrode structures
AssigneeMatsushita Electronics Corporation
InventorsShinichiro Hayashi, Tatsuo Otsuki
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Abstract
A ferroelectric thin film capacitor has smooth electrodes permitting comparatively stronger polarization, less fatigue, and less imprint, as the ferroelectric capacitor ages. The smooth electrode surfaces are produced by carefully controlled drying, soft baking, and annealing conditions.
Claims27
A thin film ferroelectric capacitor for use in integrated memories, comprising:
- a bottom electrode having a first smooth surface;
- a ferroelectric thin film layered superlattice material contacting said essentially smooth surface and having a thickness ranging from 500 Å to 2300 Å;
- and
- a top electrode over said ferroelectric thin film layered superlattice material,
- said top electrode having a second smooth surface contacting said ferroelectric thin film layered superlattice material opposite said first smooth surface,
- said first and second smooth surface respectively having essentially no surface irregularity features protruding towards said thin film ferroelectric layered superlattice material a distance greater than twenty percent of a thickness in said ferroelectric thin film layered superlattice material.
3 more elements
A ferroelectric integrated circuit memory cell comprising:
- a ferroelectric capacitor including
- a bottom electrode having a smooth surface,
- a ferroelectric thin film layered superlattice material contacting said essentially smooth surface and having a thickness ranging from 500 Å to 2300 Å, and
- a top electrode over said ferroelectric thin film layered superlattice material,
- said smooth surface being one in which all surface irregularity features protruding towards said thin film ferroelectric layered superlattice material protrude a distance less than twenty seven percent of a thickness in said ferroelectric thin film layered superlattice material;
- memory read/write means;
- and
- means for operably coupling said memory read/write with said ferroelectric capacitor.
5 more elements
A method of making a ferroelectric capacitor, said method comprising the steps of:
- forming an essentially smooth bottom electrode;
- depositing a liquid precursor on said bottom electrode to provide a precursor film, said precursor film being capable of yielding a ferroelectric layered superlattice material upon drying and annealing of said precursor film;
- drying said precursor film at a temperature less than 400° C. to provide a dried precursor residue;
- soft baking said dried precursor residue using RTP at an RTP temperature ranging from 625° C. to 725° C. for a period of time ranging from thirty seconds to five minutes to provide a soft baked precursor residue;
- and
- annealing said soft baked precursor residue in a diffusion furnace under oxygen at an anneal temperature ranging from 520° C. to 650° C.
3 more elements
Dependencies are inferred from the claim text.