# US 2001/0023937 A1 · Carbon-reinforced PC-ABS composition and articles made from same

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- Number: US 2001/0023937 A1
- Document ID: US20010023937A1
- Status: Published application
- Kind: A1
- Application number: 09/794,175
- Filed: 2001-02-27
- Published: 2001-09-27
- Earliest claimed: 2000-02-03
- Assignees: General Electric Company
- Inventors: Nirajkumar Patel
- Web page: https://patentgrep.com/patent/US20010023937A1

## CPC

- H01B 1/24: the conductive material comprising carbon-silicon compounds, carbon or silicon
- B29C 45/0001: {characterised by the choice of material}
- B29C 45/0005: {using fibre reinforcements}
- C08K 7/06: Elements
- C08L 55/02: ABS [Acrylonitrile-Butadiene-Styrene] polymers
- C08L 69/00: Compositions of polycarbonates; Compositions of derivatives of polycarbonates
- C08L 77/00: Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain (of polyhydrazides C08L79/06; of polyamideimides or polyamide acids C08L79/08); Compositions of derivatives of such polymers
- H01B: CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES (selection for magnetic properties H01F1/00; waveguides H01P {; printed circuits H05K})
- B29C: SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING (making preforms B29B11/00; making laminated products by combining previously unconnected layers which become one product whose layers will remain together B32B37/00 - B32B41/00)
- C08K: Use of inorganic or non-macromolecular organic substances as compounding ingredients (paints, inks, varnishes, dyes, polishes, adhesives C09)
- C08L: COMPOSITIONS OF MACROMOLECULAR COMPOUNDS (compositions based on polymerisable monomers C08F, C08G; artificial filaments or fibres D01F; textile treating compositions D06)

## Abstract

Carbon fiber-filled PC-ABS resin compositions which have improved electrical properties at a given level of carbon fibers, and which do not suffer from as significant a decrease in impact strength as would result from the introduction of generic carbon fibers are achieved using carbon fibers treated with a polyamide terpolymer binder. The bundles are dispersed within the PC-ABS blend. The compositions can be used for injection molding of articles for use as components in applications requiring static dissipation and/or EMI shielding. Such articles include, but are not limited to electronic devices, dust handling equipment and notebook computer enclosures.

## Claims

### Claim 1

A composition comprising:
(a) a thermoplastic resin comprising a blend of polycarbonate and acrylonitrile-butadiene-styrene copolymer; and
(b) carbon fibers associated into bundles with a polyamide terpolymer binder, said bundles being dispersed within the thermoplastic resin.

### Claim 2 (depends on 1)

The composition of claim 1, wherein the carbon fibers are present in an amount of from 5 to 50% by weight of the composition.

### Claim 3 (depends on 2)

The composition of claim 2, wherein the binder is present in an amount of from 0.5 to 10% by weight of the carbon fibers.

### Claim 4 (depends on 1)

The composition of claim 1, wherein the binder is present in an amount of from 0.5 to 10% by weight of the carbon fibers.

### Claim 5 (depends on 1)

The composition of claim 1, further comprising a flame retardant.

### Claim 6 (depends on 1)

The composition of claim 1, wherein the blend comprises polycarbonate and acrylonitrile-butadiene-styrene copolymer in a ratio of from 10:90 to 90:10, by weight.

### Claim 7 (depends on 6)

The composition of claim 6, wherein the carbon fibers are present in an amount of from 5 to 50% by weight of the composition.

### Claim 8 (depends on 7)

The composition of claim 7, wherein the binder is present in an amount of from 0.5 to 10% by weight of the carbon fibers.

### Claim 9

A method for making an injection-molded article comprising the steps of:
(a) preparing a composition comprising a thermoplastic resin comprising a blend of polycarbonate and acrylonitrile-butadiene-styrene copolymer, and carbon fibers associated into bundles with a polyamide terpolymer binder, said bundles being dispersed within the thermoplastic resin;
(b) heating the composition to melt the thermoplastic resin; and
(c) injecting the heated composition into a mold shaped to form the article.

### Claim 10 (depends on 9)

The method of claim 9, wherein the carbon fibers are present in an amount of from 5 to 50% by weight of the composition.

### Claim 11 (depends on 10)

The method of claim 10, wherein the binder is present in an amount of from 0.5 to 10% by weight of the carbon fibers.

### Claim 12 (depends on 9)

The method of claim 9, wherein the blend comprises polycarbonate and acrylonitrile-butadiene-styrene copolymer in a ratio of from 10:90 to 90:10 by weight.

### Claim 13

An injection-molded article prepared by a method comprising the steps of:
(a) preparing a composition comprising a thermoplastic resin comprising a blend of polycarbonate and acrylonitrile-butadiene-styrene copolymer, and carbon fibers associated into bundles with a polyamide terpolymer binder, said bundles being dispersed within the thermoplastic resin;
(b) heating the composition to melt the thermoplastic resin; and
(c) injecting the heated composition into a mold shaped to form the article.

### Claim 14 (depends on 13)

The article of claim 13, wherein the carbon fibers are present in an amount of from 5 to 50% by weight of the composition.

### Claim 15 (depends on 14)

The article of claim 14, wherein the binder is present in an amount of from 0.5 to 10% by weight of the carbon fibers.

### Claim 16 (depends on 13)

The article of claim 13, wherein the blend comprises polycarbonate and acrylonitrile-butadiene-styrene copolymer in a ratio of from 10:90 to 90:10 by weight.

### Claim 17

A method for increasing the impact strength of a PC-ABS blend having carbon fibers dispersed therein, comprising the step of coating the carbon fibers with a polyamide terpolymer binder prior to dispersing them in the PC-ABS blend.
