Process for preparing organohalosilanes
OwnerMikio Aramata, Kazutoshi Fujioka +1inventors
InventorsMikio Aramata, Kazutoshi Fujioka, Masahiro Yuyama
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Abstract
Organohalosilanes are prepared by reacting metallic silicon with a halogenated hydrocarbon in the presence of a copper or copper compound catalyst and an activated aluminum, aluminum alloy or aluminum carbide promotor. The reaction is carried out at a temperature of 250-400° C. in a stirred tank reactor or a fluidized bed reactor. The inventive process shortens the time required for activation in the Rochow reaction and increases the selectivity for desirable diorganodihalosilanes. The steady state is thus prolonged and conversion of the silicon enhanced, resulting in an improved reaction performance.
Claims8
An organohalosilane preparation process comprising the reaction of metallic silicon with a halogenated hydrocarbon at a temperature of 250 to 400° C. in a stirred tank reactor or a fluidized bed reactor, wherein the reaction is carried out in the presence of a copper or copper compound catalyst and at least one promotor selected from the group consisting of activated aluminum, activated aluminum alloy and activated aluminum carbide.
Dependencies are inferred from the claim text.