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US 2001/0018503 A1Published application
Fluorescent water-soluble polymers
OwnerWesley L. Whipple, Peter E. Reed +1inventors
InventorsWesley L. Whipple, Peter E. Reed, William J. Ward
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Abstract
This invention is directed to water-soluble fluorescent polymers incorporating fluorescent moieties, to a method of monitoring the water-soluble fluorescent polymers in water and to a method of controlling the dosage of a water-soluble polymeric treating agent.
Claims14
A fluorescent water-soluble polymer comprising from about 0.0001 to about 10.0 mole percent of one or more fluorescent monomer units of formula 12
- wherein 13
- is a fluorescent moiety selected from 14
- L is selected from —SO2—, —Y1C(O)—, —R2—Y1—C(O)— and —Y1—C(Z1)—Y2—(CH2)n—Y3—C(Z2)—;
- Y1 is absent, O, or NR3;
- Y2 and Y3 are independently O or NR3;
- Z1 and Z2 are independently O or S;
- Z3 and Z4 are independently OH or O−M+;
- n is an integer of from 2 to 6;
- R1 and R3 are independently hydrogen or C1-C4 alkyl;
- R2 is C1-C4 alkylene;
- X is Br, Cl or I;
- M is Na, Li or K,
- and from 90 to 99.9999 mole percent of one or more second monomer units selected from the group consisting of cationic, anionic, nonionic and zwitterionic monomers, provided that when the fluorescent water-soluble polymer consists of randomly distributed fluorescent monomer units of formula 15
- and randomly distributed second monomer units which are diallyldimethyl ammonium chloride, then R1 is C1-C4 alkyl.
11 more elements
A fluorescent monomer of formula 18
- wherein
- Y2 and Y3 are independently O or NR3;
- R1 is C1-C4 alkyl;
- n is an integer of from 2 to 6;
- and
- X is Br, Cl or I.
3 more elements
Dependencies are inferred from the claim text.