Process for preparing water-soluble or water-dispersible polyether-containing polymers and the use thereof as coating agents, binders and/or film-forming excipients in pharmaceutical dosage forms or packaging materials or as additives in cosmetic, dermatological or hygienic preparations
AssigneeBASF SE
InventorsMaximilian Angel, Michael Gotsche, Karl Kolter
Life of this patent
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Abstract
A process for preparing graft copolymers of polyvinyl esters by polymerization of a) at least one vinyl ester of aliphatic C1-C24-carboxylic acids in the presence of b) polyethers which are solid at room temperature and have the general formula I, c) and, where appropriate, at least one other monomer using a free-radical organic initiator system, wherein liquid polyalkylene glycol is used as solvent for the free-radical initiator system (feed).
Claims7
A process for preparing graft copolymers of polyvinyl esters by polymerization of
- a) at least one vinyl ester of aliphatic C1-C24-carboxylic acids in the presence of
- b) polyethers which are solid at room temperature and have the general formula I
- R1[Parenopenst]O—[Parenopenst]R2—O)u[Parenopenst]R3—O)v[Parenopenst]R4—O)w[Brketopenst]A[Parenopenst]R5—O)x[Parenopenst]R6—O)y[Parenopenst]R7—O)z[Brketclosest]SR8)nI
- in which the variables have the following meaning, independently of one another:
- R1 hydrogen, C1-C24-alkyl, R9—C(═O)—, R9—NH—C(═O)—, polyalcohol residue;
- R8 hydrogen, C1-C24-alkyl, R9—C(═O)—, R9—NH—C(═O)—;
- R2 to R7
- —(CH2)2—, —(CH2)3—, —(CH2) 4—, —CH2—CH(CH3)—, —CH2—CH(CH2—CH3)—, —CH2—CHOR10—CH2—;
- R9 C1-C24-alkyl;
- R10 hydrogen, C1-C24-alkyl, R9—C(═O)—;
- A —C(═O)—O—, —C(═O)—B—C(═O)—O—, —C(═O)—NH—B—NH—C(═O)—O—;
- B —(CH2)t—, arylene, optionally substituted;
- n 1 to 8;
- s 0 to 500;
- t 1 to 12;
- u 1 to 5000;
- v 0 to 5000;
- w 0 to 5000;
- x 1 to 5000;
- y 0 to 5000;
- z 0 to 5000
- c) and, where appropriate, at least one other monomer
- using a free-radical initiator system, wherein liquid polyalkylene glycol is used as solvent for the free-radical initiator system.
Graft copolymers of polyvinyl esters obtainable by polymerization of
- a) at least one vinyl ester of aliphatic C1-C24-carboxylic acids in the presence of
- b) polyethers which are solid at room temperature and have the general formula I
- R1[Parenopenst]O—[Parenopenst]R2—O)u[Parenopenst]R3—O)v[Parenopenst]R4—O)w[Brketopenst]A[Parenopenst]R5—O)x[Parenopenst]R6—O)y[Parenopenst]R7—O)z[Brketclosest]SR8)nI
- in which the variables have the following meaning, independently of one another:
- R1 hydrogen, C1-C24-alkyl, R9—C(═O)—, R9—NH—C(═O)—, polyalcohol residue;
- R8 hydrogen, C1-C24-alkyl, R9—C(═O)—, R9—NH—C(═O)—;
- R2 to R7
- —(CH2)2—, —(CH2)3—, —(CH2)4—, —CH2—CH(CH3)—, —CH2—CH(CH2—CH3)—, —CH2—CHOR10—CH2—;
- R9 C1-C24-alkyl;
- R10 hydrogen, C1-C24-alkyl, R9-C(═O)—;
- A —C(═O)—O—, —C(═O)—B—C(═O)—O—, —C(═O)—NH—B—NH—C(═O)—O—;
- B—(CH2)t—, arylene, optionally substituted;
- n 1 to 8;
- s 0 to 500;
- t 1 to 12;
- u 1 to 5000;
- v 0 to 5000;
- w 0 to 5000;
- x 1 to 5000;
- y 0 to 5000;
- z 0 to 5000
- c) and, where appropriate, at least one other monomer
- using a free-radical initiator system, wherein liquid polyalkylene glycol is used as solvent for the free-radical initiator system.
Dependencies are inferred from the claim text.