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US 12,760,200 B2Granted
Surface treatment agent
AssigneeDaikin Industries, Ltd.
InventorsMasatoshi Nose, Hisashi Mitsuhashi
Life of this patent
Estimating the term…
Abstract
A surface-treating agent including (I) a compound represented by the following formula (I-1) or formula (I-2) and (II) a perfluoropolyether group-containing silane compound having an OCF2 unit:
Claims15
A surface-treating agent comprising:
- (I) a compound represented by the following formula (I-1) or formula (I-2):
- wherein:
- R1 is a monovalent organic group containing a polyether chain and is represented by:
- wherein (OR2)a is a polyether chain;
- R1′ is a divalent organic group containing a polyether chain;
- the polyether chain is a chain represented by formula:
- wherein m14 is each independently an integer of 1 to 200;
- X1 is independently a silane-containing reactive crosslinkable group;
- and
- X2 independently represents a monovalent group;
- and
- (II) a perfluoropolyether group-containing silane compound having an OCF2 unit represented by the following formula (C1) and a perfluoropolyether group-containing silane compound having an OCF2 unit represented by the following formula (C2):
- wherein
- Rf is each independently an alkyl group having 1 to 16 carbon atoms optionally substituted with one or more fluorine atoms;
- PFPE is a group represented by:
- wherein e1 and f1 are each independently an integer of 1 or more and 200 or less, and the occurrence order of the respective repeating units in parenthesis with e1 or f1, is not limited in the formula;
- X107 is each independently —(CH2)s′—O—(CH2)t′—, or —CF2—(CH2)s′—O—(CH2)t′;
- s′ is an integer of 1 to 20;
- t′ is an integer of 1 to 20;
- γ is each independently an integer of 1 to 9;
- γ′ is an integer of 1 to 9;
- Ra3, at each occurrence, is each independently —Z3—SiR71pR72qR73r;
- Z3, at each occurrence, is each independently an oxygen atom or a divalent organic group;
- R71, at each occurrence, is each independently Ra′;
- Ra′ has the same meaning as Ra3;
- the number of Si atoms linearly linked via a Z3 group in Ra3 is at most 5;
- R72, at each occurrence, is each independently a hydroxyl group or a hydrolyzable group;
- R73, at each occurrence, is each independently a hydrogen atom or a lower alkyl group;
- p, at each occurrence, is each independently an integer of 0 to 3;
- q, at each occurrence, is each independently an integer of 0 to 3;
- r, at each occurrence, is each independently an integer of 0 to 3;
- provided that the sum of p, q and r with respect to (—Z3—SiR71pR72qR73r) is 3 and at least one R72 is present in formulae (C1) and (C2);
- wherein the perfluoropolyether group-containing silane compound having an OCF2 unit is a compound different from the compound represented by the formula (I-1) or formula (I-2), and
- the weight ratio of (I) to (II) is 2:8 to 9:1.
31 more elements
Dependencies are inferred from the claim text.