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US 12,759,887 B2Granted
Organosilicon precursors for deposition of silicon-containing films
AssigneeVersum Materials US, LLC
InventorsRonald M. Pearlstein, Manchao Xiao, Richard Ho, Xinjian Lei
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Abstract
A composition comprises at least one a composition comprising at least one organosilicon compound which has two or more silicon atoms connected to either a carbon atom or a hydrocarbon moiety.
Claims6
A composition comprising at least one organosilicon compound selected from the group consisting of
- wherein R3 is independently selected from the group consisting of a linear C1 to C10 alkyl group, a branched C3 to C10 alkyl group, a C3 to C10 cyclic alkyl group, a C3 to C10 heterocyclic group, a C3 to C10 alkenyl group, a C3 to C10 alkynyl group, and a C4 to C10 aryl group;
- and R4 is selected from the group consisting of hydrogen, a C1 to C10 linear alkyl group, a branched C3 to C10 alkyl group, a C3 to C10 cyclic alkyl group, a C3 to C10 heterocyclic group, a C3 to C10 alkenyl group, a C3 to C10 alkynyl group, and a C4 to C10 aryl group, wherein R3 and R4 may be linked to form a cyclic ring structure.
A method for depositing a film comprising silicon and oxygen onto a substrate, the method comprising the steps of:
- a) providing a substrate in a reactor;
- introducing into the reactor a composition comprising at least one organosilicon compound;
- c) purging the reactor with purge gas;
- d) introducing at least one of an oxygen-containing source and/or a nitrogen-containing source into the reactor;
- and
- e) purging the reactor with purge gas,
- wherein the steps b through e are repeated until a desired thickness of film is deposited;
- and
- wherein the method is conducted at one or more temperatures ranging from about 25° C. to 600° C.;
- and wherein the organosilicon compound is selected from the group consisting of
- wherein R3 is independently selected from the group consisting of a linear C1 to C10 alkyl group, a branched C3 to C10 alkyl group, a C3 to C10 cyclic alkyl group, a C3 to C10 heterocyclic group, a C3 to C10 alkenyl group, a C3 to C10 alkynyl group, and a C4 to C10 aryl group;
- and R4 is selected from the group consisting of hydrogen, a C1 to C10 linear alkyl group, a branched C3 to C10 alkyl group, a C3 to C10 cyclic alkyl group, a C3 to C10 heterocyclic group, a C3 to C10 alkenyl group, a C3 to C10 alkynyl group, and a C4 to C10 aryl group, wherein R3 and R4 may be linked to form a cyclic ring structure.
9 more elements
Dependencies are inferred from the claim text.