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US 12,747,335 B2Granted
Compositions for elastomeric compounds comprising tetrazole compatibilizing agents and tyres comprising the same
AssigneePirelli Tyre S.p.A.
InventorsLuca Giannini, Luciano Tadiello, Antonio Papagni, Mauro Monti
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Abstract
The present invention relates to compositions for elastomeric compounds for tyres, comprising monotetrazole compatibilizing agents characterised by precise activation temperatures, tyre components and tyres for vehicle wheels which comprise them. Advantageously, the present monotetrazole compatibilizing agents allow the breaking properties of the compounds to be improved while maintaining a high compatibilisation of the filler.
Claims25
An elastomeric composition for tyre compounds comprising:
- at least 100 phr of at least one diene elastomeric polymer,
- at least 1 phr of at least a reinforcing filler,
- at least 0.1 phr of at least a monotetrazole compatibilizing agent of formula (I):
- wherein
- A is absent or represents an at least divalent organic group linker, optionally comprising one or more hetero-atom(s), covalently bound to the position 2 or 5 of the tetrazole;
- R is a group covalently bound to position respectively 5 or 2 of the tetrazole, chosen from the group consisting of linear or branched C1-C10 alkyl;
- C6-C20 aryl;
- C3-C10 cycloalkyl;
- and a saturated, unsaturated or aromatic mono or bicyclic, 5- or 6-membered, optionally benzocondensated, heterocyclyl comprising at least one heteroatom chosen from the group consisting of N, S, O;
- R is optionally substituted with at least one electron withdrawing group X or an electron donor group Y;
- or R is a group B,
- B represents a group with high affinity for the reinforcing filler, chosen from the group consisting of a silane substituted with C1-C5 alkoxyls, C1-C5 alkyls and/or C6-C10 aryls, a boronic acid group with the formula (HO)2B—, a saturated, unsaturated or aromatic mono or bicyclic, 5- or 6-membered, optionally benzocondensated, heterocyclyl, comprising at least one heteroatom chosen from the group consisting of N, S and O, and an aromatic polycyclic hydrocarbon
- n is an integer ranging from 1 to 3,
- wherein groups A, B and R do not comprise any 2,5 disubstituted tetrazole;
- and
- from 0 phr to 20 phr of a vulcanising agent.
13 more elements
Dependencies are inferred from the claim text.