Method for recovering lithium and method for processing lithium ion secondary battery
AssigneeDowa Eco-System Co., Ltd.
InventorsChihiro Nishikawa, Yoshihiro Honma, Ryoei Watanabe, Masataka Yamashita, Yoshiki Ito, Yoshitaka Yoshiwara
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Abstract
Provided is a method for recovering lithium, for recovering lithium from a lithium ion secondary battery, the method including: a thermal treatment step of thermally treating a lithium ion secondary battery having a residual voltage higher than or equal to 80% of a rated voltage, to obtain a thermally treated product; a pulverizing step of pulverizing the thermally treated product, to obtain a pulverized product; and a lithium recovering step of recovering lithium from the pulverized product.
Claims10
A method for recovering lithium, for recovering lithium from a lithium ion secondary battery, the method comprising:
- thermally treating a lithium ion secondary battery having a residual voltage higher than or equal to 80% of a nominal voltage, to obtain a thermally treated product;
- pulverizing the thermally treated product, to obtain a pulverized product;
- and
- recovering lithium from the pulverized product;
- wherein
- the thermally treating comprises:
- heating the lithium ion secondary battery to 350° C. or higher and 430° C. or lower while being placed in a storing container,
- igniting the lithium ion secondary battery during a first stage of heat supply in which a first amount of heat is supplied to the lithium ion secondary battery, and
- once the lithium ion secondary battery ignites, starting a second stage of heat supply that supplies a second amount of heat to the lithium ion secondary battery, the second amount of heat being at a level that is less than or equal to 50% of the first amount of heat;
- wherein
- the storage container has an opening and an openable and closable lid, where a total area of the opening is less than or equal to 12.5% of the total surface area of the storing container with the proviso that the opening is sized to allow a hypoxic atmosphere to form in the storage container during the thermally treating.
A method for recovering lithium, for recovering lithium from a lithium ion secondary battery, the method comprising:
- thermally treating a lithium ion secondary battery having a residual voltage higher than or equal to 80% of a nominal voltage, to obtain a thermally treated product;
- pulverizing the thermally treated product, to obtain a pulverized product;
- and
- recovering lithium from the pulverized product;
- wherein
- the thermally treating comprises:
- heating the lithium ion secondary battery to 350° C. or higher and 430° C. or lower such that the lithium ion secondary battery begins to ignite, and
- after the lithium ion secondary battery finishes igniting, the lithium ion secondary battery is further thermally treated at 750° C. or higher and lower than 1,085° C.;
- wherein
- in the thermally treating, the lithium ion secondary battery is thermally treated while being placed in a storing container having a plurality of openings, where a total area of each opening of the plurality of openings is less than or equal to 6.3% of a surface area of the storing container.
Dependencies are inferred from the claim text.