Polymer-based electrolyte and a method for obtaining the same
AssigneeSabanci Universitesi
InventorsLeila Haghighi Poudeh, Mehmet Yildiz, Yusuf Ziya Menceloglu, Bekir Dizman, Serkan Unal
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Abstract
A polyoxazoline-based electrolyte and a network formed by crosslinking of the electrolyte through its secondary amine groups with an epoxy resin are provided. The network is designed as a multifunctional energy storage system that is capable of transferring mobile lithium cations through the passageways present in its structure. The present invention also relates to a method that is used to obtain such a network and electrolyte.
Claims17
A method for obtaining a network with dispersed quaternary ammonium groups, comprising the following subsequent steps:
- iii. a cationic ring-opening polymerization of a monomer with a general formula of 2-R1-2-oxazoline to obtain a polyoxazoline polymer with amide groups, wherein the R1 in the monomer is selected from the group consisting of linear aliphatic groups, branched aliphatic groups, cyclic aliphatic groups, and aromatic groups;
- iv. a hydrolysis of the polyoxazoline polymer obtained in step (i) to obtain, a first POZ chains comprising secondary amine groups in addition to the amide groups mentioned in step (i);
- x1. a partial conversion of the secondary amine groups to tertiary amine groups to obtain second POZ chains with tertiary amine groups;
- x2. a protonation of the tertiary amine groups with one or more ionic components (XY) to introduce quaternary ammonium groups with corresponding anions (Y-) to constitute a polyoxazoline-based electrolyte comprising the quaternary ammonium groups and the secondary amine groups as crosslinking sites for a formation of the network;
- iii. a crosslinking of the first POZ chains with an epoxy resin via the secondary amine groups of the first POZ chains to obtain the network.
Dependencies are inferred from the claim text.