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US 12,742,069 B2Granted
Resin composition
AssigneeKaneka Corporation
InventorsNobuyoshi Maizuru, Toshihiko Okamoto
Life of this patent
Estimating the term…
Abstract
A resin composition contains polymer particles (A) and a matrix resin (B) such that the polymer particles (A) have a graft part having a glass transition temperature of −25 °C to 18 °C. The resin composition has excellent handleability.
Claims20
A resin composition comprising:
- polymer particles (A);
- and
- a matrix resin (B),
- wherein
- the polymer particles (A) have a graft part and an elastic body,
- the graft part is a polymer that
- (i) (i-a) contains no structural unit containing an aromatic group or
- (i-b) contains, in 100% by weight of the graft part, more than 0% by weight but not more than 10% by weight of a structural unit containing an aromatic group,
- (ii) contains at least one selected from the group consisting of a structural unit derived from alkyl methacrylate and a structural unit derived from alkyl acrylate, and
- (iii) contains no structural unit containing an alkoxy group, no structural unit containing an aryloxy group, no structural unit containing an oxetane group, no structural unit containing a hydroxy group, no structural unit containing an amino group, no structural unit containing an imide group, no structural unit containing a carboxylic acid group, no structural unit containing a carboxylic anhydride group, no structural unit containing a cyclic ester group, no structural unit containing a cyclic amide group, no structural unit containing a benzoxazine group, and no structural unit containing a cyanate ester group, and
- the graft part has a glass transition temperature of −25° C. to 18° C.
- the elastic body contains at least one selected from the group consisting of diene-based rubbers and organosiloxane-based rubbers,
- the diene-based rubbers contain a structural unit derived from a diene-based monomer in an amount of 50% by weight to 100% by weight, and
- the matrix resin (B) comprises at least one type of thermosetting resin selected from the group consisting of epoxy resins, phenolic resins, polyol resins, and amino-formaldehyde resins,
- wherein the epoxy resins comprise at least one selected from the group consisting of bisphenol A epoxy resin, bisphenol F epoxy resin, bisphenol AD epoxy resin, bisphenol S epoxy resin, glycidyl ester type epoxy resin, glycidyl amine type epoxy resin, novolac type epoxy resin, hydrogenated bisphenol A epoxy resin, hydrogenated bisphenol F epoxy resin, fluorinated epoxy resin, flame-resistant epoxy resin, p-oxybenzoic acid glycidyl ether ester type epoxy resin, m-aminophenol type epoxy resin, diaminodiphenylmethane-based epoxy resin, alicyclic epoxy resin, N,N-diglycidyl aniline, N,N-diglycidyl-o-toluidine, triglycidyl isocyanurate.
12 more elements
A resin composition comprising:
- polymer particles (A);
- and
- a matrix resin (B),
- wherein
- the polymer particles (A) have a graft part and an elastic body,
- the graft part is a polymer that, in 100% by weight of the graft part,
- (i) (i-a) contains no structural unit containing an aromatic group or
- (i-b) contains more than 0% by weight but not more than 10% by weight of a structural unit containing an aromatic group, and
- (ii) (ii-a) contains at least one selected from the group consisting of a structural unit derived from alkyl methacrylate and a structural unit derived from alkyl acrylate, (ii-b) in a total amount of not less than 50% by weight,
- the graft part has a glass transition temperature of −25° C. to 18° C.,
- the polymer particles (A) are contained in an amount of 20% by weight to 50% by weight and the matrix resin (B) is contained in an amount of 50% by weight to 80% by weight, where 100% by weight represents a total amount of the polymer particles (A) and the matrix resin (B),
- the elastic body contains at least one selected from the group consisting of diene-based rubbers and organosiloxane-based rubbers,
- the diene-based rubbers contain a structural unit derived from a diene-based monomer in an amount of 50% by weight to 100% by weight, and
- the matrix resin (B) comprises at least one type of thermosetting resin selected from the group consisting of epoxy resins, phenolic resins, polyol resins, and amino-formaldehyde resins,
- wherein the epoxy resins comprise at least one selected from the group consisting of bisphenol A epoxy resin, bisphenol F epoxy resin, bisphenol AD epoxy resin, bisphenol S epoxy resin, glycidyl ester type epoxy resin, glycidyl amine type epoxy resin, novolac type epoxy resin, hydrogenated bisphenol A epoxy resin, hydrogenated bisphenol F epoxy resin, fluorinated epoxy resin, flame-resistant epoxy resin, p-oxybenzoic acid glycidyl ether ester type epoxy resin, m-aminophenol type epoxy resin, diaminodiphenylmethane-based epoxy resin, alicyclic epoxy resin, N,N-diglycidyl aniline, N,N-diglycidyl-o-toluidine, triglycidyl isocyanurate.
12 more elements
Dependencies are inferred from the claim text.