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US 12,735,780 B2Granted
Zinc or zinc-alloy coated strip or steel with improved zinc adhesion
Assigneevoestalpine Stahl GmbH
InventorsMichael Schwarzenbrunner, Katharina Steineder
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Abstract
A zinc or zinc-alloy coated rolled steel strip or sheet includes (in wt. %) 0.08-0.28 C, 1.4-4.5 Mn, 0.01-0.5 Cr, 0.01-2.5 Si, 0.01-2.0 Al. The steel has a tensile strength of 950-1550 MPa, a yield strength of 350-1400 MPa, a yield ratio≥0.35, and Ri/t≤4. The microstructure includes ≥40 tempered martensite+bainite, ≤30 fresh martensite, 5-20 retained austenite, and ≤35 polygonal ferrite. The hydrogen concentration is less than 0.2 ppm in the steel.
Claims15
A zinc or zinc-alloy coated cold rolled steel strip or sheet,
- a) having a composition comprising of in wt. %:
- C
- 0.08-0.28
- Mn
- 1.4-4.5
- Cr
- 0.01-0.5
- Si
- 0.01-2.5
- Al
- 0.01-2.0
- Si + Al
- ≥0.1
- Si + Al + Cr
- ≥0.4
- Nb
- ≤0.1
- Ti
- ≤0.1
- Mo
- ≤0.5
- Ca
- ≤0.05
- V
- ≤0.1
- Cu
- 0.06%
- Ni
- 0.08%
- B
- 0.0006%
- P[[]]
- 0.02%
- S
- 0.005%
- As
- 0.010%
- Zr
- 0.006%
- Sn
- 0.015%
- O
- 0.0003
- N
- 0.015%
- balance Fe apart from impurities;
- b) fulfilling the following conditions:
- TS tensile strength (Rm)
- 950-1550 MPa
- YS yield strength (Rp0.2)
- 350-1400 MPa
- YR yield ratio (Rp0.2/Rm)
- ≥0.35
- bendability (Ri/t)
- ≤4
- HER hole expansion ratio (λ)
- 15;
- c) having a multiphase microstructure comprising in vol %
- tempered martensite +
- bainite
- ≥40
- fresh martensite
- ≤30
- retained austenite
- 5-20
- polygonal ferrite
- ≤35;
- d) having a hydrogen concentration of less than 0.2 ppm of the steel;
- e) having a zinc or zinc-alloy coating;
- f) wherein the amount of retained austenite was measured by means of the saturation magnetization method described in detail in Proc. Int. Conf. on TRIP-aided high strength ferrous alloys (2002), Ghent, Belgium, p. 61-64;
- g) wherein the bendability is determined in accordance with JIS Z2248;
- h) wherein the yield strength and tensile strength are determined according to the European norm EN 10002 Part 1;
- i) wherein the HER (1) is determined according to ISO/WD 16630:2009 (E).
70 more elements
Dependencies are inferred from the claim text.