Light emitting device
AssigneeSamsung Display Co., Ltd.
InventorsMun-Ki Sim, Taeil Kim, Sun Young Pak, Junha Park, Jang Yeol Baek, Kyoung Sunwoo, Chanseok Oh, Minjung Jung
Life of this patent
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Abstract
A light emitting device includes a first electrode, a hole transport region disposed on the first electrode, an emission layer disposed on the hole transport region, an electron transport region disposed on the emission layer, and a second electrode disposed on the electron transport region. The emission layer includes a fused polycyclic compound represented by Formula 1.
Claims22
A light emitting device, comprising:
- a first electrode;
- a hole transport region disposed on the first electrode;
- an emission layer disposed on the hole transport region;
- an electron transport region disposed on the emission layer;
- and
- a second electrode disposed on the electron transport region, wherein
- the emission layer comprises a fused polycyclic compound represented by Formula 1, and
- the hole transport region comprises a compound represented by Formula H-a:
- wherein in Formula 1,
- X1 and X2 are each independently N(R3), O, or S,
- when X1 is S then X2 is N(R3) and when X2 is S then X1 is N(R3),
- Y1 is B,
- R1 and R2 are each independently a hydrogen atom, a deuterium atom, a halogen atom, a cyano group, a substituted or unsubstituted amine group, a substituted or unsubstituted alkyl group of 1 to 30 carbon atoms, a substituted or unsubstituted aryl group of 6 to 60 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group of 2 to 60 ring-forming carbon atoms,
- R3 is a hydrogen atom, a deuterium atom, a halogen atom, a substituted or unsubstituted alkyl group of 1 to 30 carbon atoms, a substituted or unsubstituted aryl group of 6 to 60 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group of 2 to 60 ring-forming carbon atoms, or is combined with an adjacent group to form a ring,
- n1 and n2 are each independently an integer from 0 to 6, and
- Cy1 and Cy2 are each independently a substituted or unsubstituted aromatic hydrocarbon ring of 6 to 60 ring-forming carbon atoms, or a substituted or unsubstituted aromatic heterocycle of 2 to 60 ring-forming carbon atoms, or are combined with an adjacent group to form a ring:
- wherein in Formula H-a,
- Ya and Yb are each independently C(Re1)(Rf1), N(Rg1), O, or S,
- Ar1 s a substituted or unsubstituted aryl group of 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group of 2 to 30 ring-forming carbon atoms,
- L1 and L2 are each independently a direct linkage, a substituted or unsubstituted arylene group of 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroarylene group of 2 to 30 ring-forming carbon atoms,
- Ra1 to Rg1 are each independently a hydrogen atom, a deuterium atom, a substituted or unsubstituted amine group, a substituted or unsubstituted thio group, a substituted or unsubstituted oxy group, a substituted or unsubstituted alkyl group of 1 to 20 carbon atoms, a substituted or unsubstituted alkenyl group of 2 to 20 carbon atoms, a substituted or unsubstituted aryl group of 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group of 2 to 30 ring-forming carbon atoms, or are combined with an adjacent group to form a ring,
- na and nd are each independently an integer from 0 to 4, and
- nb and nc are each independently an integer from 0 to 3.
A light emitting device, comprising:
- a first electrode;
- a second electrode facing the first electrode;
- and
- an emission layer disposed between the first electrode and the second electrode, wherein
- the emission layer comprises a host and a delayed fluorescence dopant,
- the host comprises a compound represented by Formula E-2a or Formula E-2b, and
- the delayed fluorescence dopant comprises a fused polycyclic compound represented by Formula 1:
- wherein in Formula 1,
- X1 and X2 are each independently N(R3), O, or S,
- when X1 is S then X2 is N(R3) and when X2 is S then X1 is N(R3),
- Y1 is B,
- R1 and R2 are each independently a hydrogen atom, a deuterium atom, a halogen atom, a cyano group, a substituted or unsubstituted amine group, a substituted or unsubstituted alkyl group of 1 to 30 carbon atoms, a substituted or unsubstituted aryl group of 6 to 60 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group of 2 to 60 ring-forming carbon atoms,
- R3 is a hydrogen atom, a deuterium atom, a halogen atom, a substituted or unsubstituted alkyl group of 1 to 30 carbon atoms, a substituted or unsubstituted aryl group of 6 to 60 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group of 2 to 60 ring-forming carbon atoms, or is combined with an adjacent group to form a ring,
- n1 and n2 are each independently an integer from 0 to 6, and
- Cy1 and Cy2 are each independently a substituted or unsubstituted aromatic hydrocarbon ring of 6 to 60 ring-forming carbon atoms, or a substituted or unsubstituted aromatic heterocycle of 2 to 60 ring-forming carbon atoms, or are combined with an adjacent group to form a ring:
- wherein in Formula E-2a,
- a is an integer from 0 to 10,
- La is a direct linkage, a substituted or unsubstituted arylene group of 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroarylene group of 2 to 30 ring-forming carbon atoms,
- A1 to A5 are each independently N or C(Ri),
- Ra to Ri are each independently a hydrogen atom, a deuterium atom, a substituted or unsubstituted amine group, a substituted or unsubstituted thio group, a substituted or unsubstituted oxy group, a substituted or unsubstituted alkyl group of 1 to 20 carbon atoms, a substituted or unsubstituted alkenyl group of 2 to 20 carbon atoms, a substituted or unsubstituted aryl group of 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group of 2 to 30 ring-forming carbon atoms, or are combined with an adjacent group to form a ring, and
- two or three of A1 to A5 are N, and the remainder of A1 to A5 are C(Ri), and
- wherein in Formula E-2b,
- Cbz1 and Cbz2 are each independently an unsubstituted carbazole group, or a carbazole group substituted with an aryl group of 6 to 30 ring-forming carbon atoms,
- Lb is a direct linkage, a substituted or unsubstituted arylene group of 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroarylene group of 2 to 30 ring-forming carbon atoms, and
- b is an integer from 0 to 10.
A display apparatus comprising a display panel, the display panel comprising at least one light emitting device, the light emitting device, comprising:
- a first electrode;
- a second electrode facing the first electrode;
- and
- an emission layer disposed between the first electrode and the second electrode,
- the emission layer comprising a fused polycyclic compound, the fused polycyclic compound comprising at least one selected from Compound Group 1:
A display apparatus comprising:
- a light emitting device, comprising:
- a first electrode;
- a hole transport region disposed on the first electrode;
- an emission layer disposed on the hole transport region;
- an electron transport region disposed on the emission layer;
- and
- a second electrode disposed on the electron transport region, wherein the emission layer comprises a fused polycyclic compound represented by Formula 1, and
- the hole transport region comprises a compound represented by Formula H-a:
- wherein in Formula 1,
- X1 and X2 are each independently N (R3), O, or S,
- when X1 is S then X2 is N (R3) and when X2 is S then X1 is N (R3),
- Y1 is B,
- R1 and R2 are each independently a hydrogen atom, a deuterium atom, a halogen atom, a cyano group, a substituted or unsubstituted amine group, a substituted or unsubstituted alkyl group of 1 to 30 carbon atoms, a substituted or unsubstituted aryl group of 6 to 60 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group of 2 to 60 ring-forming carbon atoms,
- R3 is a hydrogen atom, a deuterium atom, a halogen atom, a substituted or unsubstituted alkyl group of 1 to 30 carbon atoms, a substituted or unsubstituted aryl group of 6 to 60 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group of 2 to 60 ring-forming carbon atoms, or is combined with an adjacent group to form a ring,
- n1 and n2 are each independently an integer from 0 to 6, and
- Cy1 and Cy2 are each independently a substituted or unsubstituted aromatic hydrocarbon ring of 6 to 60 ring-forming carbon atoms, or a substituted or unsubstituted aromatic heterocycle of 2 to 60 ring-forming carbon atoms, or are combined with an adjacent group to form a ring:
- wherein in Formula H-a,
- Ya and Yb are each independently C (Re1) (Rf1), N (Rg1), O, or S, Ar1 is a substituted or unsubstituted aryl group of 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group of 2 to 30 ring-forming carbon atoms,
- L1 and L2 are each independently a direct linkage, a substituted or unsubstituted arylene group of 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroarylene group of 2 to 30 ring-forming carbon atoms, Ra1 to Rg1 are each independently a hydrogen atom, a deuterium atom, a substituted or unsubstituted amine group, a substituted or unsubstituted thio group, a substituted or unsubstituted oxy group, a substituted or unsubstituted alkyl group of 1 to 20 carbon atoms, a substituted or unsubstituted alkenyl group of 2 to 20 carbon atoms, a substituted or unsubstituted aryl group of 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group of 2 to 30 ring-forming carbon atoms, or are combined with an adjacent group to form a ring, na and nd are each independently an integer from 0 to 4, and nb and nc are each independently an integer from 0 to 3.
Dependencies are inferred from the claim text.