Producing ethylene by oxidatively dehydrogenating ethane
AssigneeLinde Aktiengesellschaft
InventorsMathieu Zellhuber, Martin Schubert, Andreas Meiswinkel
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Abstract
A process for producing ethylene by oxidative dehydrogenation of ethane using a shell-and-tube reactor having reaction tubes extending between a first end and a second end includes disposing one or more catalyst beds in each of the reaction tubes. In each of the reaction tubes, a ratio of a total length of the one or more catalyst beds between the first end and the second end to a diameter of each of the reaction tubes has a value between 150 and 400. The shell-and-tube reactor is operated at a linear velocity of 250 to 800 cm/s, and the one or more catalyst beds are configured such that a ratio of active catalyst mass to effective cooling area is in a range between 1.5 and 5 kg/m2.
Claims19
A method for producing ethylene by oxidative dehydrogenation of ethane, comprising:
- providing a shell-and-tube reactor having reaction tubes extending between a first end and a second end, wherein a plurality of catalyst beds are disposed in each of said reaction tubes, and in each of said reaction tubes, a ratio of a total length of the plurality of catalyst beds between said first end and said second end to a diameter of each of said reaction tubes has a value between 150 and 400;
- and
- feeding a feed comprising ethane and oxygen to the shell-and-tube reactor operating under oxidative dehydrogenation conditions;
- wherein:
- the shell-and-tube reactor is operated at a linear velocity of 250 to 800 cm/s;
- the plurality of catalyst beds are configured such that the plurality of catalyst beds in each of the reaction tubes have a different catalyst activity;
- an average ratio of active catalyst mass to effective cooling surface for the plurality of catalyst beds in each of the reaction tubes is in a range between 1.5 and 5 kg/m2, wherein in at least one of the catalyst beds in each of the reaction tubes considered individually, a ratio of active catalyst mass to effective cooling surface is in the range between 1.5 and 5 kg/m2;
- and
- the average ratio of the active catalyst mass to the effective cooling surface for the plurality of catalyst beds in each of the reaction tubes is a quotient between a sum of the active catalyst masses in all of the respective catalyst beds and the sum of all inner surfaces of the reaction tube surrounding these catalyst beds, respectively.
A plant for producing ethylene by oxidative dehydrogenation of ethane, comprising;
- a shell-and-tube reactor having reaction tubes extending between a first end and a second end, wherein:
- a plurality of catalyst beds are disposed in each of the reaction tubes;
- and
- in each of the reaction tubes, a ratio of a total length of the plurality of catalyst beds between the first end and the second end to a diameter of each of the reaction tubes has a value between 150 and 400;
- and
- a feed source configured to provide a feed comprising ethane and oxygen to the shell-and-tube reactor;
- wherein:
- the shell-and-tube reactor is configured to operate at a linear velocity of 250 to 800 cm/s;
- the plurality of catalyst beds are configured such that the plurality of catalyst beds in each of the reaction tubes have a different catalyst activity;
- and
- an average ratio of active catalyst mass to effective cooling area for the plurality of catalyst beds in each of the reaction tubes is in a range between 1.5 and 5 kg/m2, wherein in at least one of the catalyst beds in each of the reaction tubes considered individually, a ratio of active catalyst mass to effective cooling surface is in the range between 1.5 and 5 kg/m2, and
- the average ratio of the active catalyst mass to the effective cooling surface for the plurality of catalyst beds in each of the reaction tubes is a quotient between a sum of the active catalyst masses in all of the respective catalyst beds and the sum of all inner surfaces of the reaction tube surrounding these catalyst beds, respectively.
Dependencies are inferred from the claim text.