Method for producing copolymer, copolymer produced therefrom, and thermoplastic resin composition including the same
AssigneeLG Chem, Ltd.
InventorsMin Cheol Ju, Min Seung Shin, Sung Won Hong, In Soo Kim, Hyung Sub Lee
Life of this patent
Estimating the term…
Abstract
The present invention relates to a method for producing a copolymer, a copolymer produced therefrom, and a thermoplastic resin composition including the same, the method including step (S10) for adding aromatic vinyl-based monomers and vinyl cyan-based monomers to perform polymerization in the presence of polymerization initiators, wherein the polymerization initiators includes at least two different kinds of polymerization initiators, and part or all of the aromatic vinyl-based monomers are continuously divisionally added during the polymerization in step (S10).
Claims6
A method for producing a copolymer comprising step (S10) for adding aromatic vinyl-based monomers and vinyl cyan-based monomers to perform polymerization in the presence of polymerization initiators,
- wherein the polymerization initiators comprise at least two different kinds of polymerization initiators, and part of the aromatic vinyl-based monomers are continuously divisionally added while maintaining a constant rate during the polymerization in step (S10),
- wherein all the vinyl cyan-based monomers are added before the polymerization in step (S10),
- wherein the aromatic vinyl-based monomer comprises a styrene monomer substituted with an alkyl group, and
- wherein the polymerization initiators comprise t-butyl peroxybenzoate and at least one selected from the group consisting of 2,5-dimethyl-2,5-di(t-butylperoxy)hexane, di(t-butylperoxy-isopropyl)benzene, t-butyl cumyl peroxide, di-(t-amyl)-peroxide, dicumyl peroxide, butyl 4,4-di(t-butylperoxy)valerate, 2,2-di(t-butylperoxy)butane, t-amyl peroxy-benzoate, t-butylperoxy-acetate, t-butylperoxy-(2-ethylhexyl) carbonate, t-butylperoxy isopropyl carbonate, t-butyl peroxy-3,5,5-trimethyl-hexanoate, 1,1-bis(t-butylperoxy)cyclohexane, t-amyl peroxyacetate, t-amylperoxy-(2-ethylhexyl)carbonate, 1,1-di(t-butylperoxy)-3,5,5-trimethylcyclohexane, 1,1-di(t-amylperoxy)cyclohexane, t-butyl-monoperoxy-maleate and 2,2-bis(4,4-di-t-butylperoxycyclohexane)propane).
Dependencies are inferred from the claim text.