1,3-butylene glycol product
AssigneeDaicel Corporation
InventorsYasuteru Kajikawa, Tetsuro Nakanishi, Yuuichirou Hirai, Keisuke Ono, Midori Umehara, Yuki Teshima
Life of this patent
Estimating the term…
Abstract
Provided is a high-purity 1,3-butylene glycol product that is colorless and odorless, and furthermore, unlikely to be colored over time. A 1,3-butylene glycol product, having, according to a gas chromatographic analysis performed under predetermined conditions, a peak area ratio of 1000 ppm or lower appearing in a relative retention time ranging from 2.3 to 2.4, provided that the relative retention time for a peak of 1,3-butylene glycol is 1.0.
Claims14
A 1,3-butylene glycol product, having, according to a gas chromatographic analysis performed under conditions set forth below:
- 1000 ppm or lower of an area ratio of a peak appearing in a relative retention time ranging from 2.3 to 2.4, provided that the relative retention time for a peak of 1,3-butylene glycol is 1.0,
- wherein a component corresponding to the peak appearing in the range from 2.3 to 2.4 contains an acetal of 1,3-butylene glycol and acetaldol,
- wherein the 1,3-butylene glycol product is obtained by reducing a raw material for hydrogenation containing acetaldols and water,
- wherein a content of the water in the raw material for hydrogenation is from 2 to 50 wt %, and
- wherein the conditions for the gas chromatographic analysis are as follows:
- Analytical Column:
- a column with dimethylpolysiloxane as a stationary phase, having a length of 30 m, an inner diameter of 0.25 mm, and a film thickness of 1.0 μm
- Heating Conditions:
- heating from 80° C. to 120° C. at 5° C./min, then heating again to 160° C. at 2° C./min and maintaining for 2 minutes, and further heating to 230° C. at 10° C./min and maintaining at 230° C. for 18 minutes
- Sample Introduction Temperature:
- 250° C.
- Carrier Gas:
- helium
- Column Gas Flow Rate:
- 1 mL/min
- Detector and Detection Temperature:
- a flame ionization detector (FID), 280° C.
Dependencies are inferred from the claim text.