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US 12,722,125 B2Granted
Cation exchange membrane and method for producing same
AssigneeAstom Corporation
InventorsNaoto Takashina, Masayuki Kishino, Kenji Fukuta
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Abstract
A cation-exchange membrane using a polyolefin-based substrate with reduced swelling of an ion-exchange resin and a low electrical resistance is provided. The cation-exchange membrane of the present invention includes a substrate made of polyolefin-based woven fabric, and a sulfonic acid group-containing cation-exchange resin. A portion of the cation-exchange membrane other than the substrate has 23 mass % or more to 35 mass % or less of polyvinyl chloride.
Claims3
A method of producing a cation-exchange membrane, the method comprising:
- impregnating voids of a substrate made of polyolefin-based woven fabric with a polymerizable composition for forming a cation exchange resin, the polymerizable composition containing a polymerization initiator, polyvinyl chloride, and a monomer component which contains a cross-linkable monomer and a monomer containing a sulfonic acid group-introducible functional group or a sulfonic acid group;
- and
- copolymerizing the monomer component in the polymerizable composition for forming the cation-exchange resin after the immersing, wherein, the copolymerizing is performed at 40° C. or higher to lower than 80° C.,
- the polymerizable composition for forming the cation-exchange resin containing 55 parts by mass or more to 98 parts by mass or less of the polyvinyl chloride relative to 100 parts by mass of the monomer component,
- wherein:
- the monomer component includes a-alkylstyrene, and
- a content of the α-alkylstyrene is 1 mass % or more to 13 mass % or less relative to the entire monomer component.
4 more elements
Dependencies are inferred from the claim text.