Quantum cascade laser element, quantum cascade laser device, and method for manufacturing quantum cascade laser element
AssigneeHamamatsu Photonics K.K.
InventorAtsushi Sugiyama
Life of this patent
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Abstract
A quantum cascade laser element includes: a semiconductor substrate; a semiconductor laminate including an active layer and having a first end surface and a second end surface facing each other in an optical waveguide direction; a first electrode; a second electrode; and an anti-reflection film formed on the first end surface. The semiconductor laminate is configured to oscillate laser light having a central wavelength of 7.5 μm or more. The anti-reflection film includes at least one of at least one layer of a CeO2 film formed by continuous sputtering and vacuum evaporation and a plurality of layers of CeO2 films formed by discrete sputtering and vacuum evaporation.
Claims13
A quantum cascade laser element comprising:
- a semiconductor substrate;
- a semiconductor laminate formed on the semiconductor substrate, including an active layer having a quantum cascade structure, and having a first end surface and a second end surface facing each other in an optical waveguide direction;
- a first electrode formed on a surface on an opposite side of the semiconductor laminate from the semiconductor substrate;
- a second electrode formed on a surface on an opposite side of the semiconductor substrate from the semiconductor laminate;
- and
- an anti-reflection film formed on the first end surface,
- wherein the semiconductor laminate is configured to oscillate laser light having a central wavelength of 7.5 μm or more, and
- the anti-reflection film includes at least one selected from the group consisting of:
- at least one layer of a CeO2 film formed by continuous sputtering and vacuum evaporation;
- and
- a plurality of layers of CeO2 films formed by discrete sputtering and vacuum evaporation,
- in the at least one layer of the CeO2 film formed by the continuous sputtering and vacuum evaporation, a CeO2 region formed by sputtering and a CeO2 region formed by vacuum evaporation are continuous with each other, and
- in the plurality of layers of the CeO2 films formed by the discrete sputtering and vacuum evaporation, the plurality of layers of the CeO2 films are continuous with each other.
A quantum cascade laser device comprising:
- a quantum cascade laser element comprising:
- a semiconductor substrate;
- a semiconductor laminate formed on the semiconductor substrate, including an active layer having a quantum cascade structure, and having a first end surface and a second end surface facing each other in an optical waveguide direction;
- a first electrode formed on a surface on an opposite side of the semiconductor laminate from the semiconductor substrate;
- a second electrode formed on a surface on an opposite side of the semiconductor substrate from the semiconductor laminate;
- and
- an anti-reflection film formed on the first end surface,
- wherein the semiconductor laminate is configured to oscillate laser light having a central wavelength of 7.5 μm or more, and
- the anti-reflection film includes at least one selected from the group consisting of:
- at least one layer of a CeO2 film formed by continuous sputtering and vacuum evaporation;
- and
- a plurality of layers of CeO2 films formed by discrete sputtering and vacuum evaporation,
- wherein the anti-reflection film includes a body portion formed on the first end surface, and an additional portion formed on a surface on an opposite side of the second electrode from the semiconductor substrate,
- the additional portion includes a second end portion in which the more the second end portion is distant from the first end surface in the optical waveguide direction, the smaller a thickness of the second end portion is, and
- the second end portion has a second side surface intersecting the surface of the second electrode;
- a support portion supporting the quantum cascade laser element;
- and
- a joining member joining an electrode pad of the support portion and the second electrode in a state where the semiconductor substrate is located on the support portion side with respect to the semiconductor laminate,
- wherein a maximum value of a thickness of the joining member is smaller than a maximum value of a thickness of the additional portion between the electrode pad and the second electrode.
A quantum cascade laser device comprising:
- a quantum cascade laser element comprising:
- a semiconductor substrate;
- a semiconductor laminate formed on the semiconductor substrate, including an active layer having a quantum cascade structure, and having a first end surface and a second end surface facing each other in an optical waveguide direction;
- a first electrode formed on a surface on an opposite side of the semiconductor laminate from the semiconductor substrate;
- a second electrode formed on a surface on an opposite side of the semiconductor substrate from the semiconductor laminate;
- and
- an anti-reflection film formed on the first end surface,
- wherein the semiconductor laminate is configured to oscillate laser light having a central wavelength of 7.5 μm or more, and
- the anti-reflection film includes at least one selected from the group consisting of:
- at least one layer of a CeO2 film formed by continuous sputtering and vacuum evaporation;
- and
- a plurality of layers of CeO2 films formed by discrete sputtering and vacuum evaporation,
- wherein the anti-reflection film includes a body portion formed on the first end surface, and an additional portion formed on a surface on an opposite side of the first electrode from the semiconductor laminate,
- the additional portion includes a first end portion in which the more the first end portion is distant from the first end surface in the optical waveguide direction, the smaller a thickness of the first end portion is, and
- the first end portion has a first side surface intersecting the surface of the first electrode;
- a support portion supporting the quantum cascade laser element;
- and
- a joining member joining an electrode pad of the support portion and the first electrode in a state where the semiconductor laminate is located on the support portion side with respect to the semiconductor substrate,
- wherein a maximum value of a thickness of the joining member is smaller than a maximum value of a thickness of the additional portion between the electrode pad and the first electrode.
A method for manufacturing the quantum cascade laser element, the quantum cascade laser element comprising:
- a semiconductor substrate;
- a semiconductor laminate formed on the semiconductor substrate, including an active layer having a quantum cascade structure, and having a first end surface and a second end surface facing each other in an optical waveguide direction;
- a first electrode formed on a surface on an opposite side of the semiconductor laminate from the semiconductor substrate;
- a second electrode formed on a surface on an opposite side of the semiconductor substrate from the semiconductor laminate;
- and
- an anti-reflection film formed on the first end surface,
- wherein the semiconductor laminate is configured to oscillate laser light having a central wavelength of 7.5 μm or more, and
- the anti-reflection film includes at least one selected from the group consisting of:
- at least one layer of a CeO2 film formed by continuous sputtering and vacuum evaporation;
- and
- a plurality of layers of CeO2 films formed by discrete sputtering and vacuum evaporation,
- the method comprising:
- a step of preparing a laser bar including a plurality of portions each corresponding to one set of the semiconductor substrate, the semiconductor laminate, the first electrode, and the second electrode, the plurality of portions one-dimensionally arranged in a direction perpendicular to the optical waveguide direction;
- a step of performing at least one selected from the group consisting of:
- formation of at least one layer of CeO2 film by continuous sputtering and vacuum evaporation, and
- formation of a plurality of layers of CeO2 films by discrete sputtering and vacuum evaporation,
- on an end surface corresponding to the first end surface in each of the plurality of portions of the laser bar, and thereby forming an anti-reflection layer including a plurality of portions each corresponding to the anti-reflection film, on the laser bar;
- and
- a step of dividing the laser bar and the anti-reflection layer for each of the plurality of portions.
Dependencies are inferred from the claim text.