Graft polymer
AssigneeDaikin Industries, Ltd.
InventorsDaisuke Noguchi, Tetsuya Uehara, Shinichi Minami, Teruyuki Fukuda
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Abstract
An oil-resistant agent including a graft polymer obtained by graft modification of a bio-based material with a long-chain hydrocarbon group-containing non-fluorine polymer having a long-chain hydrocarbon group having 7 to 40 carbon atoms. Also disclosed is a fiber product including the graft polymer in the oil-resistant agent and a method for producing the oil-resistant agent.
Claims12
An oil-resistant agent comprising a graft polymer obtained by graft modification of a bio-based material with a long-chain hydrocarbon group-containing non-fluorine polymer having a long-chain hydrocarbon group having 7 to 40 carbon atoms,
- wherein the graft polymer has a biobased content according to ASTM D6866 of 40% or more,
- wherein the oil-resistant agent does not contain a substrate and is configured to be applied to the substrate, and
- wherein the oil-resistant agent is a water dispersion.
A method for producing an oil-resistant agent comprising a long-chain hydrocarbon group-containing non-fluorine polymer, comprising:
- a step of polymerizing a monomer containing a monomer (a) in the presence of a bio-based material, wherein the monomer (a) is represented by the following formula:
- CH2═C(—X)—C(═O)—Y(R)k
- wherein R is each independently a hydrocarbon group having 7 to 40 carbon atoms,
- X is a hydrogen atom, a monovalent organic group or a halogen atom,
- Y is a group composed of at least one selected from a divalent to tetravalent hydrocarbon group having one carbon atom, —C6H4—, —O—, —C(═O)—, —S(═O)2— or —NH—, and
- k is 1 to 3,
- wherein the long-chain hydrocarbon group-containing non-fluorine polymer is bonded to the bio-based material by graft modification to form a graft polymer,
- wherein the graft polymer has a biobased content according to ASTM D6866 of 40% or more,
- wherein the oil-resistant agent does not contain a substrate and is configured to be applied to the substrate, and
- wherein the oil-resistant agent is a water dispersion.
Dependencies are inferred from the claim text.