Organic electroluminescent material and device
AssigneeBeijing Summer Sprout Technology Co., Ltd.
InventorsMing Sang, Zhen Wang, Hongbo Li, Wei Cai, Zheng Wang, Chi Yuen Raymond Kwong, Chuanjun Xia
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Abstract
Disclosed are organic electroluminescent material and device. The organic electroluminescent material is a metal complex with a structure of Formula 1. These novel metal complexes can be used in electroluminescent device, and show more excellent performance, for example, they can reduce the driving voltage and full width at half maximum, obtain more saturated light emission, improve the efficiency and the lifetime of the device, and finally, it can improve the comprehensive performance of the device significantly.
Claims32
A metal complex, which has a structure represented by Formula 1-15:
- wherein,
- E3 is, at each occurrence identically or differently, selected from C or N;
- R1 and R2 represent, at each occurrence identically or differently, mono-substitution, multiple substitutions, or non-substitution;
- X is selected from the group consisting of:
- O, S, Se, NR″, CR″R″, SiR″R″ and GeR″R″;
- when two R″ exist at the same time, the two R″ are the same or different;
- X2, X4 to X8 are, at each occurrence identically or differently, selected from C, CRx or N;
- X11 is selected from O, S, Se or NR1;
- X31 to X34 are, at each occurrence identically or differently, selected from CR3 or N;
- at least one of X5 to X8 is selected from CRx and the Rx is a cyano group;
- R1, R2, R3, R″ and Rx are, at each occurrence identically or differently, selected from the group consisting of:
- hydrogen, deuterium, halogen, substituted or unsubstituted alkyl having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 20 ring carbon atoms, substituted or unsubstituted heteroalkyl having 1 to 20 carbon atoms, substituted or unsubstituted heterocyclic group having 3 to 20 ring atoms, substituted or unsubstituted arylalkyl having 7 to 30 carbon atoms, substituted or unsubstituted alkoxy having 1 to 20 carbon atoms, substituted or unsubstituted aryloxy having 6 to 30 carbon atoms, substituted or unsubstituted alkenyl having 2 to 20 carbon atoms, substituted or unsubstituted alkynyl having 2 to 20 carbon atoms, substituted or unsubstituted aryl having 6 to 30 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 30 carbon atoms, substituted or unsubstituted alkylsilyl having 3 to 20 carbon atoms, substituted or unsubstituted arylsilyl having 6 to 20 carbon atoms, substituted or unsubstituted alkylgermanyl having 3 to 20 carbon atoms, substituted or unsubstituted arylgermanyl having 6 to 20 carbon atoms, substituted or unsubstituted amino having 0 to 20 carbon atoms, an acyl group, a carbonyl group, a carboxylic acid group, an ester group, a cyano group, an isocyano group, a hydroxyl group, a sulfanyl group, a sulfinyl group, a sulfonyl group, a phosphino group, and combinations thereof;
- adjacent substituents R1, R2, R3, R″ and Rx can be optionally joined to form a ring.
Dependencies are inferred from the claim text.