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US 12,709,662 B2Granted
Polyimide precursor prepared by using polycyclic monomer including trifluoromethyl group and flexible polyimide obtained by using the same
AssigneeKorea Advanced Institute of Science and Technology
InventorsSang-Youl Kim, Seong-Jong Kim
Life of this patent
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Abstract
The present disclosure relates to a polyimide precursor and flexible polyimide obtained by imidization of the polyimide precursor and having high transparency, high glass transition temperature and low coefficient of thermal expansion.
Claims10
A polyimide precursor compound represented by the following Chemical Formula I:
- wherein, in the above Chemical Formula I:
- X is a combination of a dianhydride monomer represented by the following Chemical Formula 1 and a diamine monomer represented by the following Chemical Formula 2,
- Y is a combination of a dianhydride monomer represented by the following Chemical Formula 3 and the diamine monomer represented by the following Chemical Formula 2,
- a is an integer of 1 to 1,000,
- b is an integer of 1 to 1,000,
- n is an integer of 1 to 50,000,
- a:b is 80:20 or 97.5:2.5, and
- wherein, in the above Chemical Formula 1, Chemical Formula 2 and Chemical Formula 3:
- each of R1 to R4 is independently H, —CF3, a substituted or unsubstituted linear or branched C1-20 alkyl group, a substituted or unsubstituted C6-20 aryl group, or a substituted or unsubstituted C4-20 heteroaryl group containing at least one hetero atom(s) from N, O, or S,
- at least one of R1 and R2 is —CF3, the alkyl group, aryl group, or heteroaryl group substituted with —CF3,
- at least one of R3 and R4 is —CF3, the alkyl group, aryl group, or heteroaryl group substituted with —CF3, and
- A1 is represented by the following Chemical Formula 4 or Chemical Formula 5:
- wherein, in the above Chemical Formula 4 and Chemical Formula 5:
- each of R5 to R8 or R9 to R12 is independently H, —CF3, a substituted or unsubstituted linear or branched C1-20 alkyl group, a substituted or unsubstituted C6-20 aryl group, or a substituted or unsubstituted C4-20 heteroaryl group containing at least one hetero atom(s) from N, O, or S, and
- at least one of R5 to R8, or at least one of R9 to R12 is —CF3, the alkyl group, aryl group, or heteroaryl group substituted with —CF3.
12 more elements
Dependencies are inferred from the claim text.