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US 12,709,604 B2Granted
Compound, material for organic electroluminescent elements, organic electroluminescent element, and electronic device
AssigneeIdemitsu Kosan Co., Ltd.
InventorsTasuku Haketa, Yusuke Takahashi, Shota Tanaka, Hirokatsu Ito
Life of this patent
Estimating the term…
Abstract
A compound may be capable of further improving the capability of an organic EL device. An organic electroluminescent device may have a further improved device capability using such compound(s). An electronic device may include such an organic electroluminescent device. Such compounds may have formula (1) wherein the symbols are as defined in the description.
Claims18
A compound of formula if formula (1):
- wherein
- R1 to R8 each independently represent a hydrogen atom or a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms,
- provided that one selected from R1 to R4 is a single bond bonding to *a,
- adjacent two selected from R1 to R4 that are not a single bond and R5 to R8 do not bond to each other and therefore do not form a cyclic structure,
- L2 represents a single bond, a group of formula (10), or a group of formula (11);
- wherein
- R21 to R26 and R31 to R38 each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, or a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms,
- provided that:
- one selected from R21 to R26 is a single bond bonding to one selected from R1 to R4 via *a, the other one selected from R21 to R26 is a single bond bonding to the benzene ring A,
- one selected from R31 to R38 is a single bond bonding to one selected from R1 to R4 via *a, the other one selected from R31 to R38 is a single bond bonding to the benzene ring A,
- adjacent two selected from R21 to R26 that are not a single bond do not bond to each other, and therefore do not form a cyclic structure,
- adjacent two selected from R31 to R38 that are not a single bond do not bond to each other, and therefore do not form a cyclic structure,
- R41 to R44 each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, or a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms,
- a pair of adjacent two selected from R41 and R42, and R42 and R43 may bond to each other to form a substituted or unsubstituted benzene ring, or may not bond to each other and therefore may not form a benzene ring;
- R51 to R55 and R61 to R68 each independently represent a hydrogen atom, or a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms,
- provided that one selected from R51 to R55 is a single bond bonding to *b, one selected from R61 and R64 is a single bond bonding to *c,
- adjacent two selected from R51 to R55 that are not a single bond do not bond to each other and therefore do not form a cyclic structure,
- adjacent two selected from R61 to R68 that are not a single bond do not bond to each other and therefore do not form a cyclic structure:
- L1 represents a single bond, or a substituted or unsubstituted phenylene group;
- Ar represents a group selected from the formulae (20) to (22):
- wherein
- R71 to R75, R81 to R86, and R91 to R95 each independently represent a hydrogen atom or a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms,
- provided that:
- one selected from R71 to R75 is a single bond bonding to *d,
- one selected from R81 to R86 is a single bond bonding to *e, the other one selected from R81 to R86 is a single bond bonding to *f,
- ** represents a bonding position to L1,
- m is 0,
- n is 0,
- *f bonds to L1,
- adjacent two selected from R71 to R75 that are not a single bond, adjacent two selected from R81 to R86 that are not a single bond, and adjacent two selected from R91 to R95 each independently may bond to each other to form a substituted or unsubstituted cyclic structure or may not bond to each other and therefore may not form a cyclic structure;
- the benzene ring B and the benzene ring C, the benzene ring B and the benzene ring D, and the benzene ring C and the benzene ring D do not crosslink;
- wherein
- R71 to R75, R81 to R86, *d, *e, *f, **, m, and n are as defined in the formula (20),
- R111 to R118 each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, or a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms;
- provided that:
- one selected from R111 to R114 is a single bond bonding to *h;
- adjacent two selected from R111 to R114 that are not a single bond and R115 to R118 each independently may bond to each other to form a substituted or unsubstituted cyclic structure, or may not bond to each other and therefore may not form a cyclic structure;
- the benzene ring B and the benzene ring C do not crosslink;
- wherein
- R121 to R128 each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, or a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms;
- provided that one selected from R121 to R124 is a single bond bonding to *i;
- X represents CRaRb or an oxygen atom;
- one of Ra and Rb is a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, the other is a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, or Ra and Rb each are independently a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, and the two aryl groups may bond to each other via a single bond;
- ** represents a bonding position to L1, and
- adjacent two selected from R121 to R124 that are not a single bond and R125 to R128 each independently may bond to each other to form a substituted or unsubstituted cyclic structure, or may not bond to each other and therefore may not form a cyclic structure.
42 more elements
Dependencies are inferred from the claim text.