Negative electrode and secondary battery including the negative electrode
AssigneeLG Energy Solution, Ltd.
InventorsIl Jae Moon, Woo Ha Kim, Sung Soo Yoon
Life of this patent
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Abstract
Provided is a negative electrode including a negative electrode active material layer, wherein the negative electrode active material layer includes a negative electrode active material, a binder, a conductive agent, and a dispersant, wherein the conductive agent includes a carbon nanotube structure in which a plurality of single-walled carbon nanotube units are bonded side by side, the carbon nanotube structure has an average length of 1 μm to 20 μm, and QBR according to Equation 1 is in a range of 1 to 1.75 QBR = Bs / Bf . [ Equation 1 ]
Claims14
A negative electrode comprising a negative electrode active material layer,
- wherein the negative electrode active material layer comprises a negative electrode active material, a binder, a conductive agent, and a dispersant,
- wherein the conductive agent comprises a carbon nanotube structure in which a plurality of single-walled carbon nanotube units are bonded side by side,
- wherein the carbon nanotube structure has an average length of 1 μm to 20 μm, and
- wherein QBR according to Equation 1 is in a range of greater than 1 to 1.75:
- QBR
- =
- Bs
- /
- Bf
- [
- Equation
-
- 1
- ]
- wherein Bs is an average value of an amount of binder which is measured in a range from an upper surface of the negative electrode active material layer to a distance corresponding to 15% of a total thickness of the negative electrode active material layer in a direction toward a lower surface of the negative electrode active material layer, and
- Bf is an average value of an amount of binder which is measured in a range from the lower surface of the negative electrode active material layer to a distance corresponding to 15% of the total thickness of the negative electrode active material layer in a direction toward the upper surface of the negative electrode active material layer.
A method of preparing a negative electrode, the method comprising:
- preparing a conductive agent dispersion (S1);
- forming a negative electrode slurry including the conductive agent dispersion, a negative electrode active material, a binder, and a solvent (S2), wherein the preparing of the conductive agent dispersion (Sl) comprises:
- preparing a mixed solution containing a dispersion medium, a dispersant, and bundle type single-walled carbon nanotubes (Sl-1);
- and
- forming a carbon nanotube structure, in which a plurality of single-walled carbon nanotube units are bonded side by side, by dispersing the bundle type single-walled carbon nanotubes by applying a shear force to the mixed solution through a high-pressure homogenizer (Sl-2),
- wherein the carbon nanotube structure has an average length of 1 μm to 20 μm, and QBR according to Equation 1 is in a range of greater than 1 to 1.75:
- QBR
- =
- Bs
- /
- Bf
- [
- Equation
-
- 1
- ]
- the negative electrode comprises a negative electrode active material layer that is formed from the negative electrode slurry,
- wherein Bs is an average value of an amount of binder which is measured in a range from an upper surface of the negative electrode active material layer to a distance corresponding to 15% of a total thickness of the negative electrode active material layer in a direction toward a lower surface of the negative electrode active material layer, and
- wherein Bf is an average value of an amount of binder which is measured in a range from the lower surface of the negative electrode active material layer to a distance corresponding to 15% of the total thickness of the negative electrode active material layer in a direction toward the upper surface of the negative electrode active material layer.
Dependencies are inferred from the claim text.