Resist material and patterning process
AssigneeShin-Etsu Chemical Co., Ltd.
InventorJun Hatakeyama
Life of this patent
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Abstract
A resist material for use in a patterning process includes a base polymer and an acid generator, where the resist material contains, as the acid generator, a sulfonium salt or iodonium salt of a sulfonic acid bonded to a maleimide group. In a chemically amplified resist material in which an acid is used as a catalyst, it is desired to develop an acid generator that makes it possible to reduce LWR of line patterns and critical dimension uniformity (CDU) of hole patterns, and to improve sensitivity. For this purpose, it is necessary to reduce image blurs due to acid diffusion considerably. The resist material has high sensitivity and low CDU in both a positive resist material and a negative resist material.
Claims14
A resist material comprising a base polymer and an acid generator, wherein the resist material contains, as the acid generator, a sulfonium salt or iodonium salt of a sulfonic acid bonded to a maleimide group represented by the following general formula (A-1) or (A-2),
- wherein R1 and R2 each represent a hydrogen atom, a linear alkyl group having 1 to 10 carbon atoms, or a branched, or cyclic alkyl group having 3 to 10 carbon atoms, R1 and R2 optionally being bonded to each other to form a ring;
- X represents a divalent linking group containing an ester bond and having 1 to 20 carbon atoms, the linking group optionally containing an oxygen atom, a sulfur atom, a nitrogen atom, or a halogen atom;
- Rf11 to Rf14 each independently represent a hydrogen atom, a fluorine atom, an oxygen atom, a methyl group, or a trifluoromethyl group, provided that at least one of Rf11 to Rf14 is a fluorine atom or a trifluoromethyl group, and that when Rf11 and Rf12 are respectively an oxygen atom, Rf11 and Rf12 are a single oxygen atom bonded to a single carbon atom to form a carbonyl group;
- R3, R4, R5, R6, and R7 each independently represent a fluorine atom, a chlorine atom, a bromine atom, an iodine atom, or a hydrocarbyl group having 1 to 25 carbon atoms and optionally containing a heteroatom, wherein the hydrocarbyl group is saturated or unsaturated and is linear, branched, or cyclic, some or all hydrogen atoms of these groups are optionally substituted with a hydroxy group, a carboxy group, a halogen atom, a cyano group, a nitro group, a mercapto group, a sultone group, a sulfonic group, or a sulfonium salt-containing group, and some carbon atoms of these groups are optionally substituted with an ether bond, an ester bond, a carbonyl group, an amide bond, a carbonate group, or a sulfonic acid ester group;
- and R3 and R4 are optionally bonded with each other to form a ring with a sulfur atom that is bonded thereto.
Dependencies are inferred from the claim text.