Preparation of metallocene containing cationic polymers for anion exchange applications
AssigneeUniversity of South Carolina
InventorsChuanbing Tang, Tianyu Zhu
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Abstract
Chemically inert, mechanically tough, cationic metallo-polyelectrolytes designed as durable anion-exchange membranes (AEMs) via ring-opening metathesis polymerization (ROMP) of cobaltocenium-containing cyclooctene with triazole as the only linker group, followed by backbone hydrogenation to provide a new class of AEMs with a polyethylene-like framework and alkaline-stable cobaltocenium cation for ion transport, which exhibit excellent thermal, chemical and mechanical stability, as well as high ion conductivity.
Claims8
An anion-exchange membrane comprising at least one copolymer formed via a reaction scheme comprising:
Dependencies are inferred from the claim text.