Light emitting element and polycyclic compound for the same
AssigneeSamsung Display Co., Ltd.
InventorsMi Eun Jun, Seran Kim, Chanseok Oh
Life of this patent
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Abstract
A light emitting element according to an embodiment includes a first electrode, a second electrode disposed on the first electrode, and an emission layer disposed between the first electrode and the second electrode. The emission layer includes a first compound, and at least one of a second compound, a third compound, and a fourth compound. The first compound is represented by Formula 1, the second compound is represented by Formula HT-1, the third compound is represented by Formula ET-1, and the fourth compound is represented by Formula M-b. Accordingly, the light emitting element has decreased driving voltage and improved efficiency.
Claims24
A light emitting element comprising:
- a first electrode;
- a second electrode disposed on the first electrode;
- and
- an emission layer disposed between the first electrode and the second electrode, wherein
- the emission layer comprises:
- a first compound represented by Formula 1 and having a luminescence center wavelength in a range of about 440 nm to about 480 nm;
- and
- at least one of a second compound represented by Formula HT-1, a third compound represented by Formula ET-1, or a fourth compound represented by Formula M-b:
- wherein in Formula 1,
- X1 and X2 are each independently N(R0), O, or S,
- R0 is a hydrogen atom, a deuterium atom, a halogen atom, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted hydrocarbon ring group having 6 to 60 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group having 2 to 60 ring-forming carbon atoms,
- at least one of R1 to R4, R11 to R14, and R21 to R23 is each independently a group represented by Formula 2, and
- the remainder of R1 to R4, R11 to R14, and R21 to R23 are each independently a hydrogen atom, a deuterium atom, a halogen atom, a substituted or unsubstituted amine group, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted hydrocarbon ring group having 6 to 60 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group having 2 to 60 ring-forming carbon atoms:
- wherein in Formula 2,
- X3 and X4 are each independently N(R8), O, or S,
- a1 and a2 are each independently an integer from 0 to 4,
- a3 is an integer from 0 to 2,
- R5 to R8 are each independently a hydrogen atom, a deuterium atom, a halogen atom, a substituted or unsubstituted silyl group, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, or a substituted or unsubstituted aryl group having 6 to 60 ring-forming carbon atoms, and
- represents a binding site to a neighboring atom:
- wherein in Formula HT-1,
- a4 is an integer from 0 to 8, and
- R9 and R10 are each independently a hydrogen atom, a deuterium atom, a substituted or unsubstituted aryl group having 6 to 60 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group having 2 to 60 ring-forming carbon atoms:
- wherein in Formula ET-1,
- at least one of Y1 to Y3 is N,
- the remainder of Y1 to Y3 are each independently C(Ra),
- Ra is a hydrogen atom, a deuterium atom, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 60 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group having 2 to 60 ring-forming carbon atoms,
- b1 to b3 are each independently an integer from 0 to 10,
- L1 to L3 are each independently a direct linkage, a substituted or unsubstituted arylene group having 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroarylene group having 2 to 30 ring-forming carbon atoms, and
- Ar1 to Ar3 are each independently a hydrogen atom, a deuterium atom, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group having 2 to 30 ring-forming carbon atoms:
- wherein in Formula M-b,
- Q1 to Q4 are each independently C or N,
- C1 to C4 are each independently a substituted or unsubstituted hydrocarbon ring group having 5 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heterocyclic group having 2 to 30 ring-forming carbon atoms,
- e1 to e4 are each independently 0 or 1,
- L21 to L24 are each independently a direct linkage,
- a substituted or unsubstituted divalent alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted arylene group having 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroarylene group having 2 to 30 ring-forming carbon atoms,
- d1 to d4 are each independently an integer from 0 to 4, and
- R31 to R39 are each independently a hydrogen atom, a deuterium atom, a halogen atom, a cyano group, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group having 2 to 30 ring-forming carbon atoms, or are bonded to an adjacent group to form a ring.
A polycyclic compound represented by Formula 1:
- wherein in Formula 1,
- X1 and X2 are each independently N(R0), O, or S,
- R0 is a hydrogen atom, a deuterium atom, a halogen atom, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted hydrocarbon ring group having 6 to 60 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group having 2 to 60 ring-forming carbon atoms,
- at least one of R1 to R4, R11 to R14, and R21 to R23 is each independently a group represented by Formula 2, and
- the remainder of R1 to R4, R11 to R14, and R21 to R23 are each independently a hydrogen atom, a deuterium atom, a halogen atom, a substituted or unsubstituted amine group, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted hydrocarbon ring group having 6 to 60 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group having 2 to 60 ring-forming carbon atoms:
- wherein in Formula 2,
- X3 and X4 are each independently N(R8), O, or S,
- a1 and a2 are each independently an integer from 0 to 4,
- a3 is an integer from 0 to 2,
- R5 to R8 are each independently a hydrogen atom, a deuterium atom, a halogen atom, a substituted or unsubstituted silyl group, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, or a substituted or unsubstituted aryl group having 6 to 60 ring-forming carbon atoms, and
- represents a binding site to a neighboring atom, and
- wherein the polycyclic compound has a luminescence center wavelength in a range of about 440 nm to about 480 nm.
A polycyclic compound selected from Compound Group 1:
- wherein in Compound Group 1,
- D is a deuterium atom, and
- Ph is a phenyl group.
Dependencies are inferred from the claim text.