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US 12,686,800 B2Granted
Adhesive agent composition, surface protection film, and method of manufacturing organic light-emitting electronic device
AssigneeXinmei Fontana Holding (Hong Kong) Limited
InventorsJeong Min Choi, Hyun Cheol Kim, Sojin Kim, Hyungoo Kang, Jae Seung Lim
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Abstract
The present disclosure relates to an adhesive composition comprising a urethane polymer; an acryl-based polymer; and a curing agent, wherein the acryl-based polymer comprises a (meth)acrylate monomer comprising silicone; and a (meth)acrylate monomer comprising a hydroxyl group as a monomer unit, a surface protective film, and a method for manufacturing an organic light emitting electronic device.
Claims4
An adhesive composition comprising:
- a urethane polymer;
- an acryl-based polymer;
- and
- a curing agent,
- wherein the acryl-based polymer comprises monomer units derived from a (meth) acrylate monomer comprising silicone;
- and a (meth) acrylate monomer comprising a hydroxyl group,
- wherein the acryl-based polymer comprises a copolymer of:
- (i) 70% by weight to 98.9% by weight of an alkyl (meth) acrylate monomer having less than 8 carbon atoms;
- (ii) 0.1% by weight to 10% by weight of the (meth) acrylate monomer comprising silicone;
- and
- (iii) 1% by weight to 20% by weight of the (meth) acrylate monomer comprising a hydroxyl group,
- wherein the acryl-based polymer is included in an amount of 1 parts by weight to 10 parts by weight with respect to 100 parts by weight of the urethane polymer,
- wherein the (meth) acrylate monomer comprising silicone has a number average molecular weight of 500 g/mol to 10,000 g/mol
- wherein the urethane polymer has a weight average molecular weight of 60,000 g/mol to 160,000 g/mol, and
- wherein the monomer unit derived from the (meth) acrylate monomer comprising silicone is represented by Chemical Formula 3:
- wherein, in Chemical Formula 3,
- R1 to R7 are the same as or different from each other, and each independently an alkyl group;
- R8 is hydrogen or a methyl group;
- n is an integer of 0 or greater;
- and
- L is a linear or branched divalent saturated hydrocarbon group;
- a divalent monocyclic aliphatic saturated hydrocarbon group;
- a divalent polycyclic saturated hydrocarbon group;
- a divalent aromatic hydrocarbon group;
- a divalent group of a ring having cyclic saturated hydrocarbon fused to aromatic hydrocarbon;
- —O—;
- —C(═O)—;
- —C(═O)—O—;
- —S—;
- or a group linking two or more of the groups thereof;
- wherein the urethane polymer is obtained by curing a urethane composition comprising a polyol and a multifunctional isocyanate compound;
- wherein the polyol comprises 2 to 6 hydroxyl groups, wherein an equivalence ratio of an isocyanate group to a hydroxyl group (NCO/OH) in the urethane composition is greater than or equal to 0.1 and less than 1, wherein the urethane polymer has a hydroxyl group value of 3 mgKOH/g to 15 mgKOH/g, and wherein the acryl-based polymer has a hydroxyl group value of 5 mgKOH/g to 40 mgKOH/g.
29 more elements
Dependencies are inferred from the claim text.