Polyimide binder precursor composition, and power storage device using same
AssigneeUbe Corporation
InventorsKeisuke Morimoto, Nobu Iizumi, Shohei Inoue, Sousuke Honma
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Abstract
A polyimide binder from which a high-capacity power storage device, which has a small irreversible capacity and a high initial charge/discharge efficiency and is lightweight, can be obtained. The polyimide binder precursor composition is a polyimide binder precursor composition for a power storage device electrode, and includes a reaction product of a tetracarboxylic acid component and a diamine component, and a solvent. The polyimide binder obtained from the polyimide binder precursor composition has an irreversible capacity of 1200 mAh/g or less.
Claims12
A polyimide binder precursor composition for a power storage device electrode, comprising a reaction product of a tetracarboxylic acid component and a diamine component, and a solvent,
- wherein a polyimide binder obtained from the polyimide binder precursor composition has an irreversible capacity of 1200 mAh/g or less, wherein
- the tetracarboxylic acid component comprises more than 80 mol % of an alicyclic tetracarboxylic dianhydride based on the total amount of the tetracarboxylic acid component, wherein the alicyclic tetracarboxylic dianhydride is selected from the group consisting of:
- wherein R31 is a direct bond or a divalent organic group, and R41, R46 and R47 are each independently selected from the group consisting of —CH2—, —CH═CH—, —CH2CH2—, —O— and —S—;
- and
- the diamine component comprises, based on the total amount of the diamine component,
- more than 80 mol % of an aromatic diamine compound, wherein the aromatic diamine compound is selected from compounds represented by formula:
- wherein W1 is a divalent group selected from the group consisting of:
- and a divalent group selected from formula (6):
- wherein R61 to R68 each independently represents any one of the divalent groups selected from the group consisting of:
- n12 and n13 each independently represent an integer of 0 to 4;
- and
- R52 and R53 are each independently an alkyl group having 1 to 6 carbon atoms, a halogen group, a hydroxyl group, a carboxyl group, or a trifluoromethyl group.
Dependencies are inferred from the claim text.