Epoxy resin and electrodeposition paint
AssigneeKansai Paint Co., Ltd.
InventorsShinji Tsushima, Noriyuki Yamada, Takashi Iwai
Life of this patent
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Abstract
An epoxy resin, which is obtained by reacting at least a compound having one or more epoxy groups and a compound having a functional group that reacts with the epoxy groups, satisfies conditions (I) and/or (II): (I) the compound having a functional group that reacts with the epoxy groups includes a trihydric or higher phenol compound and/or a compound including a trifunctional or higher polyisocyanate; (II) the epoxy resin has an average degree of polyfunctionalization (X1) per molecule, as expressed by Formula (1), of 0.30 or more: Average degree of polyfunctionalization (X1)=number of ends per molecule of epoxy resin−2. Formula (1):
Claims18
An amino-containing epoxy resin obtained by reacting a first epoxy resin and an amine compound, said first epoxy resin being obtained, without a dimer acid diglycidyl ester, by reacting at least:
- a compound having two or more epoxy groups;
- and
- a compound having a functional group that reacts with the epoxy groups,
- wherein the amino-containing epoxy resin has an average degree of polyfunctionalization (X2), as expressed by Formula (3) below, of 0.60 to 13.0:
- Formula (3):
- Average degree of polyfunctionalization (X2)=number of ends in one molecule of amino-containing epoxy resin-2,
- wherein the compound having two or more epoxy groups is comprised of:
- an epoxy compound represented by Formula (D):
- where n is 0 to 8;
- and/or
- an epoxy compound obtained by reaction of polyphenol compounds and epihalohydrin,
- wherein the first epoxy resin satisfies conditions (I) and/or (II) below:
- (I) the compound having a functional group that reacts with the epoxy groups comprises a trihydric or higher phenol compound and/or a compound including a trifunctional or higher polyisocyanate, wherein the trihydric or higher phenol compound includes a compound represented by structural formula (A) below:
- where n is an integer of 1 to 20, p is an integer of 0 to 4, q is an integer of 0 to 3, and r is an integer of 0 to 4;
- R1 to R3 are each independently a monovalent group;
- R2's in n repeating units may be different from each other;
- when a plurality of R1's, R2's, and/or R3's are present in aromatic rings, the plurality of R1's, R2's, and/or R3's may be the same or different from each other;
- and R1 to R3 may be bonded to each other to form a ring,
- (II) the first epoxy resin has an average degree of polyfunctionalization (X1) per molecule, as expressed by Formula (1) below, of 0.60 to 13.0:
- Average degree of polyfunctionalization (X1)=number of ends per molecule of epoxy resin−2, Formula (1):
- wherein the number of ends per molecule of epoxy resin refers to the number of ends having an epoxy group or a functional group that reacts with the epoxy group in one molecule of the first epoxy resin, which is the number of functional group-containing molecular ends resulting from branching of a main chain of the first epoxy resin in which an epoxy group of the compound having two or more epoxy groups and a secondary hydroxyl group of another compound having two or more epoxy groups are reacted with each other.
Dependencies are inferred from the claim text.