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US 12,679,906 B2Granted
Method for manufacturing fluoroelastomers
AssigneeSYENSQO SPECIALTY POLYMERS ITALY S.p.A.
InventorsDaniela Bertani, Matteo Fantoni, Mirko Tavano
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Abstract
The present invention relates to a method for manufacturing fluoroelastomers having iodinated/brominated chain ends, notably vinylidene fluoride (VDF)-based fluoroelastomers, in emulsion polymerization whereas no addition of fluorosurfactants or hydrogenated surfactants is required, and to a fluoroelastomers which can be obtained from said method.
Claims9
A method of making a fluoroelastomer (A), which is a (per)fluoroelastomer comprising Iodine and/or Bromine chain ends, said method comprising
- polymerizing vinylidene fluoride (VDF), in the presence of at least one second (per)fluorinated monomer (MF) different from VDF, in an aqueous emulsion in the presence of a chain transfer agent (CTA-X) having I and/or Br atoms and in the presence of a redox-initiating system (R) comprising at least one organic radical initiator (O) and at least one composition (CS) comprising at least one compound (S) bearing at least one sulfinic acid group,
- wherein:
- the amount of initiator (O) is of at least 1.50 and at most 15.00 mmol of O2 per kg of fluoroelastomer (A);
- the amount of compound(S) is of at least 0.20 and at most 2.00 g per kg of fluoroelastomer (A);
- and
- the ratio between agent (CTA-X) and composition (CS) is of at least 2.00 and of at most 8.00 g of X/g of composition (CS), whereas X is the amount of I and/or Br in the agent (CTA-X);
- and
- wherein said emulsion polymerization is carried out without addition of any fluorinated surfactant or hydrogenated surfactant.
5 more elements
Dependencies are inferred from the claim text.