Two-dimensional polymeric fullerene and preparation method thereof
AssigneeInstitute of Chemistry, Chinese Academy of Sciences
InventorsJian Zheng, Xueping Cui, Lingxiang Hou, Lingxin Luo
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Abstract
The present disclosure relates to a two-dimensional polymeric fullerene and preparation method thereof, wherein the preparation method includes the following steps: providing metal intercalated polymeric fullerene; replacing metal ions in the metal intercalated polymeric fullerene with quaternary ammonium salts. The preparation method of the two-dimensional polymeric fullerene of an embodiment of the present application has simple process and low cost, which can achieve large-scale preparation of two-dimensional polymeric fullerene.
Claims11
A two-dimensional polymeric fullerene, in which adjacent fullerene molecules are connected with each other through covalent bonds, showing a regular topological structure of repeated arrangement;
- wherein, each fullerene cluster is connected with four fullerene clusters, and is connected with two of the fullerene clusters through one C—C single bond respectively, while is connected with the other two of the fullerene clusters through two C—C single bonds respectively, and the four carbon atoms in the two C—C single bonds form a quaternary ring structure.
A preparation method for two-dimensional polymeric fullerene, comprising the following steps:
- providing metal intercalated polymeric fullerene;
- and
- replacing metal ions in the metal intercalated polymeric fullerene with quaternary ammonium salts;
- wherein in the two-dimensional polymeric fullerene, adjacent fullerene molecules are connected with each other through covalent bond, showing a regular topological structure of repeated arrangement.
A polymeric fullerene crystal, in which adjacent fullerene molecules are connected by covalent bonds, showing a regular topological structure of a repeating arrangement of carbon clusters, without metal intercalated,
- wherein, each fullerene cluster is connected with four fullerene clusters, and is connected with two of the fullerene clusters through one C—C single bond respectively, while is connected with the other two of the fullerene clusters through two C—C single bonds respectively, and the four carbon atoms in the two C—C single bonds form a quaternary ring structure.
An electronic device comprising a two-dimensional polymeric fullerene;
- wherein in the two-dimensional polymeric fullerene, adjacent fullerene molecules are connected with each other through covalent bond, showing a regular topological structure of repeated arrangement, and
- wherein, each fullerene cluster is connected with four fullerene clusters, and is connected with two of the fullerene clusters through one C—C single bond respectively, while is connected with the other two of the fullerene clusters through two C—C single bonds respectively, and the four carbon atoms in the two C—C single bonds form a quaternary ring structure.
Dependencies are inferred from the claim text.