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US 12,679,008 B2Granted
Method for making UV and HEVL-absorbing ophthalmic lenses
AssigneeAlcon Inc.
InventorsFrank Chang, Troy Vernon Holland, Houliang Tang, Adam K. Sniady
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Abstract
Described herein is a cost-effective and time-efficient method for producing UV- and HEVL-absorbing silicone hydrogel contact lenses capable of blocking ultra-violet (“UV”) radiation and high-energy-violet light (HEVL) with wavelengths from 380 nm to 440 nm, thereby protecting eyes to some extent from damages caused by UV and HEVL radiation. This invention also provides UV- and HEVL-absorbing absorbing contact lenses made according to a method of the invention.
Claims20
A method for producing UV-absorbing silicone hydrogel contact lenses,
- the method comprising the steps of:
- (1) providing a mold for making a soft contact lens, wherein the mold has a first mold half with a first molding surface defining the anterior surface of a contact lens and a second mold half with a second molding surface defining the posterior surface of the contact lens, wherein said first and second mold halves are configured to receive each other such that a cavity is formed between said first and second molding surfaces;
- (2) introducing a lens-forming composition into the cavity, wherein the lens-forming composition comprises
- (i) at least one hydrophilic vinylic monomer,
- (ii) at least one siloxane-containing vinylic monomer and/or at least one polysiloxane vinylic crosslinker,
- (iii) at least one polymerizable UV-absorbing compound and at least one polymerizable HEVL-absorbing compound in amounts sufficient to provide the lens-forming composition with an average UVB transmittance of about 10% or less between 280 and 315 nanometers, an average UVA transmittance of about 30% or less between 315 and 380 nanometers, and an average Violet transmittance of about 70% or less between 380 nm and 440 nm,
- (iv) from about 0.05% to about 1.5% by weight of at least one acyltin photoinitiator capable of initiating a free-radical polymerization under irradiation with a light source including a light in the region of from 455 nm to 510 nm,
- (v) at least one photochromic compound that is polymerizable and comprises an ethylenicaly-unsaturated group;
- and
- (3) irradiating the lens-forming composition in the mold by using the light source including a light in a region of from 455 nm to 510 nm, so as to form the UV- and HEVL-absorbing silicone hydrogel contact lens, wherein the formed UV-absorbing silicone hydrogel contact lens has a UVB transmittance of about 10% or less between 280 and 315 nanometers and a UVA transmittance of about 30% or less between 315 and 380 nanometers and and the Violet transmittance of about 70% or less between 380 nm and 440 nm.
7 more elements
Dependencies are inferred from the claim text.