Polymerized high-molecular-weight sterically hindered amine and preparation method thereof
AssigneeBeijing Tiangang Auxiliary Co., Ltd.
InventorsJingjing An, Wei Chen, Yongnian Gao, Jing Li, Gang Liu
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Abstract
The present invention discloses a polymerized high-molecular-weight sterically hindered amine having a general formula I, the sterically hindered amine has the advantages of high molecular weight, difficult migration in polymer products, good thermal stability, etc., and can stabilize and/or be flame retardant to organic substances sensitive to light, heat or oxidation, and furthermore, can be made to have better compatibility with different types of polymer materials by changing substituents.
Claims6
A polymerized high-molecular-weight sterically hindered amine, wherein the polymerized high-molecular-weight sterically hindered amine is selected from the following structures:
- mn is an integer between 2-20;
- Q1, Q2 and Q3 are independently selected from —O—, —CO—O—, —CO—NR22— or —NR22—;
- R22 is independently selected from hydrogen and C1-C20 alkyl;
- R1 and R2 are independently selected from hydrogen, and C1-C40 alkyl, wherein any one or more of the H atoms in the alkyl can be substituted with —R21, —OR21, —COOR21 or —COR21;
- R3 is selected from C1-C40 alkylene, wherein any one or more of the H atoms in the alkylene can be substituted with —R21, —OR21, —COOR21 or —COR21;
- the total number of carbon atoms in —R1, R2 and R3 is 40 or less;
- R7 and R8 are independently selected from hydrogen, unsubstituted C1-C20 alkyl or C1-C20 alkyl substituted with —R21;
- or, R7, R8 and the N atom between R7 and R8 form unsubstituted C3-C12 cycloalkylene or C2-C12 heterocycloalkylene;
- R4 and R5 are independently selected from hydrogen, and C1-C40 alkyl, wherein any one or more of the H atoms in the alkyl can be substituted with —R21, —OR21, —COOR21 or —COR21;
- R6 is selected from C1-C40 alkylene, wherein any one or more of the H atoms in the alkylene can be substituted with —R21, —OR21, —COOR21 or —COR21;
- and the total number of carbon atoms in —R4, R5 and R6 is 40 or less;
- and
- R12 and R13 are independently selected from hydrogen, unsubstituted C4-C30 alkyl or C4-C30 alkyl wherein any one or more of the H atoms in the alkyl can be subsiitute with hydroxyl, —NO2, halogen, amino, cyano, —R21, —OR21, —COOOR21, —COR21 or C1-C10 alkyl,
- R21 is selected from C1-C20 alkyl.
Dependencies are inferred from the claim text.