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US 12,673,942 B2Granted
Azabicyclyl-substituted heterocycles as fungicides
AssigneeBayer Aktiengesellschaft
InventorsJulie Geist, Anthony Millet, Cyril Montagne, Lionel Nicolas, Dominique Loque, Vincent Thomas, Mazen Es-Sayed, Alexander Sudau
Life of this patent
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Abstract
The present disclosure relates to azabicyclyl-substituted heterocyclic compounds of formula (I), wherein A1, A2, m, R3, R4, R5, L, R6, T, the ring Y, p, R7 and Q have the meanings as defined in the specification, to compositions comprising such compounds, to processes and intermediates for their preparation as well as the uses thereof for controlling phytopathogenic microorganisms, such as phytopathogenic fungi.
Claims13
A compound of formula (I):
- wherein
- A1 is N or CR8;
- A2 is O, S, C(═O), S(═O), S(═O)2, NR1 or CR2AR2B,
- wherein
- R1, R2A and R2B are independently from each other hydrogen, C1-C6-alkyl or C3-C8-cycloalkyl,
- wherein C1-C6-alkyl is optionally substituted with one to three substituents independently selected from the group consisting of halogen, cyano, amino, nitro, hydroxyl, formyl, carboxyl, C1-C6-alkoxy, C1-C6-haloalkoxy, C1-C6-alkoxycarbonyl, C3-C8-cycloalkyl, C3-C8-halocycloalkyl, —O—Si(C1-C6-alkyl)3 and 3- to 7-membered heterocyclyl,
- and
- wherein C3-C8-cycloalkyl is optionally substituted with one to three substituents independently selected from the group consisting of halogen, cyano, nitro, hydroxyl, formyl, oxo, methylidene, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-halo-alkoxy, C2-C6-alkenyl, C3-C8-cycloalkyl, C3-C8-halocycloalkyl, —O—Si(C1-C6-alkyl)3 and 3- to 7-membered heterocyclyl,
- or
- R2A and R2B form together with the carbon atom to which they are attached to a C3-C8-cycloalkyl-ring or a 3- to 7-membered heterocyclyl-ring,
- m is 0, 1 or 2,
- R3 and R4 are independently hydrogen, halogen, cyano, hydroxyl, formyl, carboxyl, C1-C6-alkyl, C1-C6-alkoxy, C1-C6-alkylcarbonyl, C1-C6-alkoxycarbonyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C8-cycloalkyl, C6-C14-aryl, 5- to 14-membered heteroaryl, 3- to 14-membered heterocyclyl or —O—Si(C1-C6-alkyl)3,
- wherein C1-C6-alkyl, C1-C6-alkoxy, C1-C6-alkylcarbonyl, C1-C6-alkoxycarbonyl, C2-C6-alkenyl, C2-C6-alkynyl and —O—Si(C1-C6-alkyl)3 are optionally substituted with one to three substituents independently selected from the group consisting of halogen, cyano, amino, nitro, hydroxyl, formyl, carboxyl, C1-C6-alkoxy, C1-C6-haloalkoxy, C1-C6-alkoxycarbonyl, C3-C8-cycloalkyl, C3-C8-halocycloalkyl, —O—Si(C1-C6-alkyl)3 and 3- to 7-membered heterocyclyl,
- and
- wherein C3-C8-cycloalkyl, C6-C14-aryl, 5- to 14-membered heteroaryl and 3- to 14-membered heterocyclyl are optionally substituted with one to three substituents independently selected from the group consisting of halogen, cyano, nitro, hydroxyl, formyl, oxo, methylidene, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-halo-alkoxy, C2-C6-alkenyl, C3-C8-cycloalkyl, C3-C8-halocycloalkyl, —O—Si(C1-C6-alkyl)3 and 3- to 7-membered heterocyclyl,
- or
- R3 and R4 form together with the carbon atom to which they are attached to a carbonyl, a methylidene, a C3-C8-cycloalkyl-ring or a 3- to 7-membered heterocyclyl-ring,
- wherein C3-C8-cycloalkyl-ring and 3- to 7-membered heterocyclyl-ring are optionally substituted with one to three substituents independently selected from the group consisting of halogen, cyano, nitro, hydroxyl, formyl, oxo, methylidene, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy, C2-C6-alkenyl, C3-C8-cycloalkyl, C3-C8-halocycloalkyl, —O—Si(C1-C6-alkyl)3 and 3- to 7-membered heterocyclyl,
- R5 is hydrogen, hydroxyl, C1-C6-alkyl, C1-C6-alkoxy, C1-C6-alkylcarbonyloxy, C1-C6-alkyl-sulfanyl, C1-C6-alkylsulfinyl, C1-C6-alkylsulfonyl, C3-C8-cycloalkyl or —O—Si(C1-C6-alkyl)3, wherein C1-C6-alkyl, C1-C6-alkoxy, C1-C6-alkylcarbonyloxy, C1-C6-alkylsulfanyl, C1-C6-alkylsulfinyl, C1-C6-alkylsulfonyl and —O—Si(C1-C6-alkyl)3 are optionally substituted with one to three substituents independently selected from the group consisting of halogen, cyano, amino, nitro, hydroxyl, formyl, carboxyl, C1-C6-alkoxy, C1-C6-haloalkoxy, C1-C6-alkoxy-carbonyl, C3-C8-cycloalkyl, C3-C8-halocycloalkyl, —O—Si(C1-C6-alkyl)3 and 3- to 7-membered heterocyclyl,
- and
- wherein C3-C8-cycloalkyl is optionally substituted with one to three substituents independently selected from the group consisting of halogen, cyano, nitro, hydroxyl, formyl, oxo, methylidene, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy, C2-C6-alkenyl, C3-C8-cycloalkyl, C3-C8-halocycloalkyl, —O—Si(C1-C6-alkyl)3 and 3- to 7-membered heterocyclyl,
- or
- R3 and R5 or R4 and R5 form together with the carbon atoms to which they are attached to a C3-C8-cycloalkyl-ring,
- T is hydrogen, hydroxyl, C1-C6-alkyl, —C(═O)R9, —C(═O)(OR10), C(═O)N(R11)2, —S(═O)R12, —S(═O)2R13 or —S(═O)2N(R14)2,
- wherein
- R9 and R10 are independently C1-C6-alkyl, C1-C6-haloalkyl, C3-C8-cycloalkyl or C2-C6-alkenyl,
- R11, R12, R13 and R14 are independently hydrogen, C1-C6-alkyl, C1-C6-haloalkyl, C3-C8-cycloalkyl or C2-C6-alkenyl,
- L is a direct bond, carbonyl, C1-C6-alkylene, C2-C6-alkenylene, C2-C6-alkynylene, —C(═O)—C1-C6-alkylene-, —C1-C6-alkylene-C(═O)—, —NRL1—, —NRL2(C═O)—, —C(═O)NRL3—, —NRL4S(═O)2—, —S(═O)2NRL5—, —C(═NORL6)—, —C(═N—N(RL7)2)—, —C(═NRL8)— or a group of formula
- wherein
- said C1-C6-alkylene, C2-C6-alkenylene, C2-C6-alkynylene, —C(═O)—C1-C6-alkylene- and —C1-C6-alkylene-C(═O)— are optionally substituted with one to three substituents LSA,
- # is the point of attachment to the heterocyclyl-moiety,
- ## is the point of attachment to R6,
- L1 is a direct bond or C1-C6-alkylene,
- L2 is a direct bond or C1-C6-alkylene,
- E is C3-C8-cycloalkyl, C3-C8-cycloalkenyl or 3- to 7-membered heterocyclyl,
- wherein said C3-C8-cycloalkyl, C3-C8-cycloalkenyl and 3- to 7-membered heterocyclyl in turn are optionally substituted with one to three substituents LSC,
- RL1, RL2, RL3 and RL4 are independently hydrogen or C1-C6-alkyl,
- RL5, RL6, RL7 and RL8 are independently hydrogen, C1-C6-alkyl, C1-C6-haloalkyl, C3-C8-cycloalkyl or C2-C6-alkenyl,
- LSA is independently halogen, cyano, hydroxyl, carboxyl, methylidene, halomethylidene, C1-C6-alkoxy, C1-C6-haloalkoxy, C3-C8-cycloalkyl, C3-C8-halocycloalkyl, C1-C6-alkoxycarbonyl, —O—Si(C1-C6-alkyl)3 or 3- to 7-membered heterocyclyl,
- and/or
- two substituents LSA that are bound to the same carbon atom form together with the carbon atom which they are attached to a C3-C8-cycloalkyl-ring or a 3- to 7-membered heterocyclyl-ring,
- LSC is independently halogen, cyano, nitro, hydroxyl, formyl, carboxyl, oxo, methylidene, halomethylidene, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy, C2-C6-alkenyl, C3-C8-cycloalkyl, C3-C8-halocycloalkyl, —O—Si(C1-C6-alkyl)3 or 3- to 7-membered heterocyclyl,
- and/or
- two LSC substituents form together with the carbon atom(s) to which they are attached to a C3-C8-cycloalkyl-ring,
- R6 is C3-C12-carbocyclyl, C6-C14-aryl, 3- to 14-membered heterocyclyl, 5- to 14-membered hetero-aryl, C3-C12-carbocyclyloxy, C6-C14-aryloxy, 5- to 14-membered heteroaryloxy, 3- to 14-membered heterocyclyloxy, C3-C12-carbocyclylsulfanyl, C6-C14-arylsulfanyl, 5- to 14-membered heteroarylsulfanyl, 3- to 14-membered heterocyclylsulfanyl, C3-C12-carbocyclyl-sulfinyl, C6-C14-arylsulfinyl, 5- to 14-membered heteroarylsulfinyl, 3- to 14-membered hetero-cyclylsulfinyl, C3-C12-carbocyclylsulfonyl, C6-C14-arylsulfonyl, 5- to 14-membered heteroaryl-sulfonyl, 3- to 14-membered heterocyclylsulfonyl, C1-C3-alkoxy, C1-C3-haloalkoxy, C1-C3-alkylsulfanyl, C1-C3-alkylsulfinyl or C1-C3-alkylsulfonyl,
- wherein C1-C3-alkoxy, C1-C3-haloalkoxy, C1-C3-alkylsulfanyl, C1-C3-alkylsulfinyl and C1-C3-alkylsulfonyl are substituted with one substituent selected from the group consisting of C3-C12-carbocyclyl, C6-C14-aryl, 3- to 14-membered heterocyclyl and 5- to 14-membered heteroaryl,
- wherein said C3-C12-carbocyclyl, C6-C14-aryl, 3- to 14-membered heterocyclyl and 5- to 14-membered heteroaryl in turn are optionally substituted with one to four R6S substituents,
- wherein C3-C12-carbocyclyl, C6-C14-aryl, 3- to 14-membered heterocyclyl, 5- to 14-membered heteroaryl, C3-C12-carbocyclyloxy, C6-C14-aryloxy, 5- to 14-membered heteroaryloxy, 3- to 14-membered heterocyclyloxy, C3-C12-carbocyclylsulfanyl, C6-C14-arylsulfanyl, 5- to 14-membered heteroarylsulfanyl, 3- to 14-membered heterocyclylsulfanyl, C3-C12-carbocyclyl-sulfinyl, C6-C14-arylsulfinyl, 5- to 14-membered heteroarylsulfinyl, 3- to 14-membered hetero-cyclylsulfinyl, C3-C12-carbocyclylsulfonyl, C6-C14-arylsulfonyl, 5- to 14-membered heteroaryl-sulfonyl and 3- to 14-membered heterocyclylsulfonyl are optionally substituted with one to four R6S substituents,
- wherein
- R6S is independently selected from the group consisting of halogen, cyano, isocyano, nitro, hydroxyl, mercapto, pentafluorosulfanyl, oxo, methylidene, halomethylidene, formyl, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-halo-alkynyl, C2-C6-alkenyloxy, C2-C6-haloalkenyl-oxy, C2-C6-alkylnyloxy, C2-C6-haloalkylnyloxy, C1-C6-alkylsulfanyl, C1-C6-haloalkyl-sulfanyl, C3-C8-cycloalkylsulfanyl, C1-C6-alkylsulfinyl, C1-C6-haloalkylsulfinyl, C3-C8-cycloalkyl-sulfinyl, C1-C6-alkylsulfonyl, C1-C6-haloalkylsulfonyl, C3-C8-cyclo-alkylsulfonyl, C3-C8-cycloalkyl, C3-C8-cycloalkyloxy, C3-C8-cycloalkenyl, C6-C14-aryl, 5- or 6-membered heteroaryl, 3- to 7-membered heterocyclyl, —N(R15)2, —O(C═O)R16, —C(═O)R16, —C(═O)(OR17), —C(═O)N(R18)2, —S(═O)2N(R19)2, —O—Si(C1-C6-alkyl)3 and —Si(C1-C6-alkyl)3,
- wherein C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-haloalkynyl, C2-C6-alkenyl-oxy, C2-C6-haloalkenyloxy, C2-C6-alkylnyloxy, C2-C6-haloalkylnyloxy, C1-C6-alkylsulfanyl, C1-C6-haloalkylsulfanyl, C1-C6-alkylsulfinyl, C1-C6-haloalkyl-sulfinyl, C1-C6-alkylsulfonyl, C1-C6-haloalkylsulfonyl, —O—Si(C1-C6-alkyl)3 and —Si(C1-C6-alkyl)3 are furthermore optionally substituted with one to three substituents independently selected from the group consisting of cyano, hydroxyl, C1-C6-alkoxy, C1-C6-haloalkoxy, —O—Si(C1-C6-alkyl)3, —Si(C1-C6-alkyl)3, C3-C8-cycloalkyl, C3-C8-halocycloalkyl and 3- to 7-membered heterocyclyl,
- or
- two substituents C1-C6-alkyl attached to the same carbon atom form together with the carbon atom to which they are attached to a C3-C8-cycloalkyl-ring,
- and
- wherein C3-C8-cycloalkylsulfanyl, C3-C8-cycloalkylsulfinyl, C3-C8-cycloalkyl-sulfonyl, C3-C8-cycloalkyl, C3-C8-cycloalkyloxy, C3-C8-cycloalkenyl, C6-C14-aryl, 5- or 6-membered heteroaryl and 3- to 7-membered heterocyclyl are furthermore optionally substituted with one to four substituents independently selected from the group consisting of halogen, cyano, nitro, hydroxyl, formyl, carboxyl, oxo, methylidene, halomethylidene, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy, C1-C6-alkoxycarbonyl, C1-C6-haloalkoxy-carbonyl, C2-C6-alkenyl, C3-C8-cycloalkyl and C3-C8-halocycloalkyl,
- and wherein
- R15 is independently hydrogen, C1-C6-alkyl or C3-C8-cycloalkyl,
- wherein said C1-C6-alkyl in turn is optionally substituted with one to three substituents independently selected from the group consisting of halogen, cyano, hydroxyl, C1-C6-alkoxy, C1-C6-haloalkoxy, —O—Si(C1-C6-alkyl)3, —Si(C1-C6-alkyl)3, C3-C8-cycloalkyl, C3-C8-halocycloalkyl and 3- to 7-membered heterocyclyl,
- and
- wherein said C3-C8-cycloalkyl in turn is optionally substituted with one to four substituents independently selected from the group consisting of halogen, cyano, nitro, hydroxyl, formyl, carboxyl, oxo, methylidene, halomethylidene, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy, C1-C6-alkoxy-carbonyl, C1-C6-haloalkoxycarbonyl, C2-C6-alkenyl, C3-C8-cycloalkyl and C3-C8-halocycloalkyl,
- R16, R17, R18 and R19 are independently hydrogen, C1-C6-alkyl or C1-C6-haloalkyl,
- wherein said C1-C6-alkyl and C1-C6-haloalkyl in turn are optionally substituted with one to three substituents independently selected from the group consisting of cyano, hydroxyl, C1-C6-alkoxy, C1-C6-haloalkoxy, —O—Si(C1-C6-alkyl)3, —Si(C1-C6-alkyl)3, C3-C8-cycloalkyl, C3-C8-halocycloalkyl and 3- to 7-membered heterocyclyl,
- the ring Y forms together with the pyridine- or pyridazine-ring respectively a bicyclic hetero-cyclyl or a bicyclic heteroaryl,
- p is 0, 1, 2, 3 or 4,
- R7 is hydrogen, halogen, cyano, isocyano, hydroxyl, mercapto, nitro, amino, formyl, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-hydroxyalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy, C1-C6-alkylcarbonyl, C1-C6-haloalkylcarbonyl, C1-C6-alkoxycarbonyl, C1-C6-haloalkoxycarbonyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-haloalkynyl, C2-C6-alkenyloxy, C2-C6-haloalkenyl-oxy, C2-C6-alkynyloxy, C2-C6-haloalkynyloxy, C1-C6-alkylsulfanyl, C1-C6-haloalkylsulfanyl, C3-C8-cycloalkylsulfanyl, C2-C6-alkenylsulfanyl, C2-C6-alkynylsulfanyl, C1-C6-alkylsulfinyl, C1-C6-haloalkylsulfinyl, C3-C8-cycloalkylsulfinyl, C1-C6-alkylsulfonyl, C1-C6-haloalkyl-sulfonyl, C3-C8-cycloalkylsulfonyl, C3-C8-cycloalkyl, C3-C6-cycloalkenyl, 3- to 7-membered heterocyclyl, C3-C8-cycloalkyloxy, —O—Si(C1-C6-alkyl)3, —Si(C1-C6-alkyl)3, —N(R20)2, —C(═NR21)R22, —NR23C(═O)R24, —C(═O)(OR25), —C(═O)N(R26)2, —S(═O)2N(R27)2 or —S(═O)(═NR28)R29,
- wherein C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-hydroxyalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy, C1-C6-alkylcarbonyl, C1-C6-haloalkylcarbonyl, C1-C6-alkoxycarbonyl, C1-C6-haloalkoxy-carbonyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-haloalkynyl, C2-C6-alkenyl-oxy, C2-C6-haloalkenyloxy, C2-C6-alkynyloxy, C2-C6-haloalkynyloxy, C1-C6-alkylsulfanyl, C1-C6-haloalkylsulfanyl, C2-C6-alkenylsulfanyl, C2-C6-alkynylsulfanyl, C1-C6-alkylsulfinyl, C1-C6-haloalkylsulfinyl, C1-C6-alkylsulfonyl, C1-C6-haloalkylsulfonyl, —O—Si(C1-C6-alkyl)3 and —Si(C1-C6-alkyl)3 are optionally substituted with one to three R7Sa substituents,
- wherein C3-C8-cycloalkylsulfanyl, C3-C8-cycloalkylsulfinyl, C3-C8-cycloalkylsulfonyl, C3-C8-cycloalkyl, C3-C6-cycloalkenyl, 3- to 7-membered heterocyclyl, C3-C8-cycloalkyloxy are optionally substituted with one to three R7Sc substituents,
- and wherein
- R20 is independently hydrogen, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-haloalkynyl, C3-C8-cycloalkyl, C3-C8-halo-cycloalkyl or 3- to 7-membered heterocyclyl,
- wherein C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C2-C6-alkenyl, C2-C6-halo-alkenyl, C2-C6-alkynyl and C2-C6-haloalkynyl in turn are optionally substituted with one to three substituents R7Sa,
- and
- wherein C3-C8-cycloalkyl, C3-C8-halocycloalkyl and 3- to 7-membered heterocyclyl in turn are optionally substituted with one to three substituents R7Sc,
- R21 and R22 are independently hydroxyl, amino, cyano, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, mono-(C1-C6-alkyl)amino or di-(C1-C6-alkyl)amino,
- wherein C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, mono-(C1-C6-alkyl)-amino and di-(C1-C6-alkyl)amino in turn are optionally substituted with one to three R7Sa substituents,
- R23, R24, R25, R26, R27, R28 and R29 are independently hydrogen, C1-C6-alkyl, C1-C6-halo-alkyl and C3-C8-cycloalkyl,
- wherein C1-C6-alkyl and C1-C6-haloalkyl in turn are optionally substituted with one to three R7Sa substituents,
- and
- wherein C3-C8-cycloalkyl in turn is optionally substituted with one to three R7Sc substituents,
- wherein
- R7Sa is independently cyano, hydroxyl, carboxyl, C1-C6-alkoxy, C1-C6-haloalkoxy, C3-C8-cycloalkyl, C3-C8-halocycloalkyl, C1-C6-alkoxycarbonyl, —O—Si(C1-C6-alkyl)3, —Si(C1-C6-alkyl)3 or 3- to 7-membered heterocyclyl,
- R7Sc is independently halogen, cyano, nitro, hydroxyl, formyl, oxo, methylidene, halomethylidene, C1-C6-alkyl, C1-C6-haloalkyl C1-C6-alkoxy, C1-C6-haloalkoxy, C2-C6-alkenyl, C3-C8-cycloalkyl, C3-C8-halocycloalkyl, —O—Si(C1-C6-alkyl)3 or 3- to 7-membered heterocyclyl,
- or
- two R75c substituents that are bound to the same carbon atom form together with the carbon atom to which they are attached to a C3-C8-cycloalkyl-ring,
- or
- two R7 substituents form together with the carbon atoms to which they are attached to a C3-C8-cycloalkyl-ring,
- R8 is hydrogen or halogen,
- Q is C6-C14-aryl, C3-C12-carbocyclyl, 3- to 14-membered heterocyclyl or 5- to 14-membered heteroaryl,
- wherein C6-C14-aryl, C3-C12-carbocyclyl, 3- to 14-membered heterocyclyl or 5- to 14-membered heteroaryl are optionally substituted with one to five substituents QS,
- wherein
- QS is independently selected from the group consisting of halogen, cyano, isocyano, nitro, hydroxyl, mercapto, formyl, carboxyl, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkylcarbonyl, C1-C6-haloalkylcarbonyl, C1-C6-alkoxy, C1-C6-haloalkoxy, C1-C6-alkoxycarbonyl, C1-C6-haloalkoxycarbonyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-haloalkynyl, C2-C6-alkenyloxy, C2-C6-haloalkenyloxy, C1-C6-alkylsulfanyl, C1-C6-haloalkylsulfanyl, C1-C6-alkylsulfinyl, C1-C6-haloalkylsulfinyl, C1-C6-alkylsulfonyl, C1-C6-haloalkylsulfonyl, C3-C8-cycloalkyl, C3-C8-cycloalkyloxy, C3-C6-cycloalkenyl, 3- to 7-membered heterocyclyl, C6-C14-aryl, 5- to 14-membered heteroaryl, —O—Si(C1-C6-alkyl)3, —Si(C1-C6-alkyl)3, —O—C(═O)R30, —NR31C(═O)R32, —C(═O)N(R33)2, C(═S)R34, —C(═S) N(R35)2, —C(═NR36)R37, —C(═NOR38)R39 and —N(R40)2,
- wherein
- said C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkylcarbonyl, C1-C6-haloalkyl-carbonyl, C1-C6-alkoxy, C1-C6-haloalkoxy, C1-C6-alkoxy-C1-C6-alkyl, C1-C6-alkoxycarbonyl, C1-C6-haloalkoxycarbonyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-haloalkynyl, C2-C6-alkenyloxy, C2-C6-haloalkenyloxy, C1-C6-alkylsulfanyl, C1-C6-haloalkylsulfanyl, C1-C6-alkylsulfinyl, C1-C6-haloalkylsulfinyl, C1-C6-alkylsulfonyl, C1-C6-haloalkylsulfonyl, —O—Si(C1-C6-alkyl)3 and —Si(C1-C6-alkyl)3 in turn are optionally substituted with one to three substituents independently selected from the group consisting of cyano, amino, nitro, hydroxyl, C1-C6-alkoxy, C1-C6-haloalkoxy, C1-C6-alkoxycarbonyl, C1-C6-haloalkoxycarbonyl, C3-C8-cycloalkyl, C3-C8-halocycloalkyl, —Si(C1-C6-alkyl)3 and 3- to 7-membered heterocyclyl,
- and said C3-C8-cycloalkyl, C3-C8-cycloalkoxy, C3-C6-cycloalkenyl, 3- to 7-membered heterocyclyl and 5- to 14-membered heteroaryl in turn are optionally substituted with one to three substituents independently selected from the group consisting of halogen, cyano, amino, nitro, hydroxyl, formyl, carboxyl, oxo, methylidene, halomethylidene, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy, C1-C6-alkoxycarbonyl, C1-C6-halo-alkoxycarbonyl, C3-C8-cycloalkyl, C3-C8-halocycloalkyl, C2-C6-alkenyl and 3- to 7-membered heterocyclyl,
- wherein said C3-C8-cycloalkyl, C3-C8-halocycloalkyl and 3- to 7-membered heterocyclyl furthermore are optionally substituted with two substituents forming together with the carbon atom(s) to which they are attached to a C3-C8-cycloalkyl,
- and wherein
- R30, R31, R32, R33, R34, R35, R36, R37, R38 and R39 are independently hydrogen, C1-C6-alkyl, C1-C6-haloalkyl or C1-C6-alkoxy,
- wherein
- said C1-C6-alkyl, C1-C6-haloalkyl and C1-C6-alkoxy in turn are optionally substituted with one to three substituents independently selected from the group consisting of cyano, amino, nitro, hydroxyl, C1-C6-alkoxy, C1-C6-haloalkoxy, C1-C6-alkoxycarbonyl, C1-C6-halo-alkoxycarbonyl, C3-C8-cycloalkyl, C3-C8-halocycloalkyl, —Si(C1-C6-alkyl)3 and 3- to 7-membered heterocyclyl,
- and wherein
- R40 is hydrogen, hydroxyl, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C2-C6-alkenyl, C2-C6-haloalkenyl or C3-C8-cycloalkyl,
- wherein said C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C2-C6-alkenyl and C2-C6-haloalkenyl in turn are optionally substituted with one to three substituents independently selected from the group consisting of cyano, amino, nitro, hydroxyl, C1-C6-alkoxy, C1-C6-haloalkoxy, C1-C6-alkoxycarbonyl, C1-C6-haloalkoxycarbonyl, C3-C8-cycloalkyl, C3-C8-halocycloalkyl, —Si(C1-C6-alkyl)3 and 3- to 7-membered heterocyclyl,
- and wherein said C3-C8-cycloalkyl in turn is optionally substituted with one to three substituents independently selected from the group consisting of halogen, cyano, amino, nitro, hydroxyl, formyl, carboxyl, oxo, methylidene, halomethylidene, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy, C1-C6-alkoxycarbonyl, C1-C6-halo-alkoxycarbonyl, C3-C8-cycloalkyl, C3-C8-halocycloalkyl, C2-C6-alkenyl and 3- to 7-membered heterocyclyl,
- wherein said C3-C8-cycloalkyl, C3-C8-halocycloalkyl and 3- to 7-membered heterocyclyl furthermore are optionally substituted with two substituents forming together with the carbon atom(s) to which they are attached to a C3-C8-cycloalkyl,
- or
- two QS substituents that are bound to the same carbon atom form together with the carbon atom to which they are attached to a C3-C8-cycloalkyl-ring,
- as well as N-oxides, salts, hydrates and hydrates of the salts and N-oxides thereof.
103 more elements
Dependencies are inferred from the claim text.