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US 12,673,937 B2Granted
Light-emitting device including heterocyclic compound and electronic apparatus including light-emitting device
AssigneeSamsung Display Co., Ltd.
InventorsHankyu Pak, Dongjun Kim, Minji Kim, Eunjae Jeong, Sanghyun Han, Byeongwook Yoo, Sohee Jo, Hyunbin Park
Life of this patent
Estimating the term…
Abstract
A light-emitting device includes: a first electrode; a second electrode facing the first electrode; an interlayer between the first electrode and the second electrode, the interlayer including an emission layer; and a heterocyclic compound represented by Formula 1: Formula 1 may be understood by referring to the description of Formula 1 provided herein. An electronic apparatus may include the light-emitting device.
Claims20
A light-emitting device comprising:
- a first electrode;
- a second electrode facing the first electrode;
- an interlayer between the first electrode and the second electrode, the interlayer comprising an emission layer;
- and
- a heterocyclic compound represented by Formula 1:
- wherein, in Formulae 1 to 4,
- Y2 is a group represented by Formula 2,
- ring CY3 is a group represented by Formula 3,
- ring CY4 is a group represented by Formula 4,
- ring CY21, ring CY22, ring CY31, ring CY32, ring CY41, and ring CY42 are each independently a C3-C60 carbocyclic group or a C1-C60 heterocyclic group,
- X33 is a single bond, O, S, B(R33), N(R33), C(R33)(R34), Si(R33)(R34), or C(R33)═C(R34),
- b33 is an integer from 0 to 3,
- when b33 is 0, X33 is not present,
- X43 is a single bond, O, S, B(R43), N(R43), C(R43)(R44), Si(R43)(R44), or C(R43)═C(R44),
- b43 is an integer from 0 to 3,
- when b43 is 0, X43 is not present,
- R1, R21 to R23, R31 to R34, and R41 to R44 are each independently hydrogen, deuterium, —F, —Cl, —Br, —I, a hydroxyl group, a cyano group, a nitro group, a C1-C60 alkyl group unsubstituted or substituted with at least one R10a, a C2-C60 alkenyl group unsubstituted or substituted with at least one R10a, a C2-C60 alkynyl group unsubstituted or substituted with at least one R10a, a C1-C60 alkoxy group unsubstituted or substituted with at least one R10a, a C3-C60 carbocyclic group unsubstituted or substituted with at least one R10a, a C1-C60 heterocyclic group unsubstituted or substituted with at least one R10a, a C6-C60 aryloxy group unsubstituted or substituted with at least one R10a, a C6-C60 arylthio group unsubstituted or substituted with at least one R10a, a C7-C60 aryl alkyl group unsubstituted or substituted with at least one R10a, a C2-C60 heteroaryl alkyl group unsubstituted or substituted with at least one R10a, —Si(Q1)(Q2)(Q3), —N(Q1)(Q2), —B(Q1)(Q2), —C(═O)(Q1), —S(═O)2(Q1), or —P(═O)(Q1)(Q2),
- a21, a22, a31, a32, a41, and a42 are each independently an integer from 0 to 10,
- wherein, in Formula 2,
- * indicates a binding site to nitrogen (N) bound to Y2 in Formula 1,
- wherein, in Formulae 3 and 4,
- *′ indicates a binding site to nitrogen (N) bound to Y2 in Formula 1, and
- *″ indicates a binding site to nitrogen (N) bound to R1 in Formula 1,
- wherein R10a is:
- deuterium, —F, —Cl, —Br, —I, a hydroxyl group, a cyano group, or a nitro group;
- a C1-C60 alkyl group, a C2-C60 alkenyl group, a C2-C60 alkynyl group, or a C1-C60 alkoxy group, each unsubstituted or substituted with deuterium, —F, —Cl, —Br, —I, a hydroxyl group, a cyano group, a nitro group, a C3-C60 carbocyclic group, a C1-C60 heterocyclic group, a C6-C60 aryloxy group, a C6-C60 arylthio group, a C7-C60 aryl alkyl group, a C2-C60 heteroaryl alkyl group, —Si(Q11)(Q12)(Q13), —N(Q11)(Q12), —B(Q11)(Q12), —C(═O)(Q11), —S(═O)2(Q11), —P(═O)(Q11)(Q12), or any combination thereof;
- a C3-C60 carbocyclic group, a C1-C60 heterocyclic group, a C6-C60 aryloxy group, a C6-C60 arylthio group, a C7-C60 aryl alkyl group, or a C2-C60 heteroaryl alkyl group, each unsubstituted or substituted with deuterium, —F, —Cl, —Br, —I, a hydroxyl group, a cyano group, a nitro group, a C1-C60 alkyl group, a C2-C60 alkenyl group, a C2-C60 alkynyl group, a C1-C60 alkoxy group, a C3-C60 carbocyclic group, a C1-C60 heterocyclic group, a C6-C60 aryloxy group, a C6-C60 arylthio group, a C7-C60 aryl alkyl group, a C2-C60 heteroaryl alkyl group, —Si(Q21)(Q22)(Q23), —N(Q21)(Q22), —B(Q21)(Q22), —C(═O)(Q21), —S(═O)2(Q21), —P(═O)(Q21)(Q22), or any combination thereof;
- or
- —Si(Q31)(Q32)(Q33), —N(Q31)(Q32), —B(Q31)(Q32), —C(═O)(Q31), —S(═O)2(Q31), or —P(═O)(Q31)(Q32), and
- wherein Q1 to Q3, Q11 to Q13, Q21 to Q23, and Q31 to Q33 are each independently:
- hydrogen;
- deuterium;
- —F;
- —Cl;
- —Br;
- —I;
- a hydroxyl group;
- a cyano group;
- a nitro group;
- a C1-C60 alkyl group, a C2-C60 alkenyl group, a C2-C60 alkynyl group, a C1-C60 alkoxy group, a C3-C60 carbocyclic group or a C1-C60 heterocyclic group, each unsubstituted or substituted with deuterium, —F, a cyano group, a C1-C60 alkyl group, a C1-C60 alkoxy group, a phenyl group, a biphenyl group, a C1-C60 heterocyclic group, or any combination thereof;
- a C7-C60 aryl alkyl group;
- or a C2-C60 heteroaryl alkyl group.
39 more elements
Dependencies are inferred from the claim text.