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US 12,669,494 B2Granted
Sulfur and amorphous dithiazine measurement
AssigneeConocoPhillips Company
InventorJay Locklear
Life of this patent
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Abstract
The disclosure describes a method to indirectly measure the amount of elemental sulfur or amorphous dithiazine in a reservoir sample by converting them to H2S gas. The H2S is captured via caustic cyanide solution and quantified by analytical methods and correspond to the concentration of elemental sulfur or amorphous dithiazine. The method has particular applicability to determine where best to drill and avoid locations of high sulfur.
Claims6
A method of producing oil, said method comprising:
- a) obtaining a plurality of samples, each sample from a known location in an oil reservoir and containing MEA or a triazine, or MEA or a triazine being added thereto;
- b) optionally analyzing each of said plurality of samples or portion thereof to determine a first amount of H2S remaining unreacted with said MEA or triazine after step a);
- c) analyzing each of said plurality of samples or portion thereof to determine an amount of dithiazine and correlating said amount of dithiazine to a second amount of H2S;
- d) analyzing each of said plurality of samples or portion thereof for an amount of amorphous dithiazine (a-DTZ) by treatment with a reductive mercaptan solution to convert a-DZT to H2S and measuring a third amount of H2S and correlating said third amount of H2S to said amount of a-DTZ in said plurality of samples;
- e) calculating a total amount of H2S in a each sample from a each said known location by adding said optional first amount of H2S from step b), said second amount of H2S from step c), and said third amount of H2S from step d), thereby determining one or more highest H2S content location(s) in said reservoir and one or more sweeter content location(s);
- f) producing oil from said one or more sweeter content location(s) as determined in step e);
- and
- g) wherein said produced oil has less H2S than a method of producing oil from said reservoir without steps a) through f).
5 more elements
Dependencies are inferred from the claim text.