System and method for using ultramicroporous carbon for the selective removal of nitrate with capacitive deionization
AssigneeLawrence Livermore National Security, LLC
InventorsPatrick Campbell, Maira Ceron Hernandez, Steven Hawks, Colin Loeb, Tuan Anh Pham, Michael Stadermann
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Abstract
The present disclosure relates to a method for making a carbon aerogel electrode material. The method involves initially making a wet organic sol-gel form. The sol-gel form is carbonized at a temperature of from about 900° C. to about 1000° C., for from about 2 hours to about 4 hours. The carbonized sol-gel is then activated under carbon dioxide flow, for from about 0.5 hour to about 1.5 hours, at from about 900° C. to about 1000° C.
Claims4
A method for making a carbon aerogel electrode material having slit-shaped pores forming first pores, and a plurality of second pores, the method comprising:
- making a wet organic sol-gel block;
- slicing the wet organic sol-gel block into sheets each having a thickness of about 300 μm to about 700 μm, to form wet sol-gel sheets;
- washing the wet sol-gel sheets with DI water and subsequently exchanged for acetone;
- sandwich wet sol-gel sheets between porous silicon carbide sheets, to create a sol-gel form;
- drying the sol-gel form to form a dried sol-gel form;
- carbonizing the dried sol-gel form at a temperature of from about 900° C. to about 1000° C., for from about 2 hours to about 4 hours;
- activating the carbonized sol-gel under carbon dioxide flow, for from about 0.5 hour to about 1.5 hours, at from about 900° C. to about 1000° C., while being exposed to a CO2 flow of about 2 liters per minute in a furnace;
- and
- wherein the slit-shaped pores are below 1 nm in width, and the plurality of second pores form micron-sized pores, and wherein the second pores help to form a ligament-like structure having a plurality of ligaments formed with a random distribution throughout a thickness of the carbon aerogel electrode material, and the slit-shaped pores are present on the ligaments.
Dependencies are inferred from the claim text.