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US 12,662,587 B2Granted
Biodegradable compositions and articles made from cellulose acetate
AssigneeEastman Chemical Company
InventorsWayne Ken Shih, Stephanie Kay Clendennen, Jeffrey Michael Clauson, Gaurav Amarpuri
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Abstract
A thermoformable and biodegradable cellulose acetate composition comprising at least one cellulose acetate and either polyethylene glycol or m ethoxy polyethylene glycol are disclosed. The compositions are formed into films, sheets, and articles.
Claims14
A composition comprising:
- (1) a cellulose acetate,
- wherein the cellulose acetate has an acetyl degree of substitution (“DSAc”) in the range of from 2.2 to 2.6, and wherein the number average molecular weight (“Mn”) of the cellulose acetate is between 20,000 and 100,000, wherein the Mn is measured using gel permeation chromatography with a polystyrene equivalent and using N-methyl-2-pyrrolidone (NMP) as the solvent,
- (2) from 17-23 wt % of a polyethylene glycol 400 (“PEG400”), and
- (3) a stabilizer, which comprises a combination of (i) a secondary antioxidant which is a phosphite compound;
- and (ii) one or more primary antioxidants, (iii) citric acid, or a combination thereof,
- wherein the secondary antioxidant is present at from 0.01 to 0.8 wt %,
- wherein the primary antioxidant is present at from 0.05 to 0.7 wt %,
- wherein the citric acid is present at from 0.05 to 0.2 wt %,
- all weight percentage is based on the total weight of the composition,
- wherein the composition is melt processable, biodegradable, and disintegrable.
7 more elements
Dependencies are inferred from the claim text.