Polymerizable composition, polymer, ultraviolet shielding material, laminate, compound, ultraviolet absorbing agent, and method of producing compound
AssigneeFUJIFILM Corporation
InventorsYoshihiro Jimbo, Daisuke Sasaki
Life of this patent
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Abstract
Provided is a polymerizable composition including a compound represented by Formula (1), and an ultraviolet absorbing agent A having a maximum absorption wavelength on a shorter wavelength side than a maximum absorption wavelength of the compound represented by Formula (1). Provided are a polymer, an ultraviolet shielding material, a laminate, a compound, an ultraviolet absorbing agent, and a method of producing a compound. In Formula (1), R1 to R6 each independently represent a hydrogen atom or a substituent, where at least one of R1 to R6 represents a group that contains a polymerizable group having an ethylenically unsaturated bond.
Claims18
A polymerizable composition comprising:
- a compound represented by Formula (1);
- and
- an ultraviolet absorbing agent A having a maximum absorption wavelength on a shorter wavelength side than a maximum absorption wavelength of the compound represented by Formula (1),
- in Formula (1), R1 to R6 each independently represent a hydrogen atom or a substituent,
- R1 and R2 may be bonded to each other to form a ring, and
- R3 and R4 may be bonded to each other to form a ring,
- where at least one of R1 to R6 represents a group that contains a polymerizable group having an ethylenically unsaturated bond.
A compound which is represented by Formula (5),
- in Formula (5), R51 and R52 each independently represent a hydrogen atom, an alkyl group, or an aryl group,
- R53 represents an alkyl group and R54 represents a hydrogen atom,
- X51 and X52 each independently represent —O—, —OC(═O)O—, or —OC(═O)NH—,
- Y51 and Y52 each independently represent a single bond or a divalent linking group, the divalent linking group is a hydrocarbon group or a group having a structure in which two or more hydrocarbon groups are bonded via a linking group, and the linking group represents —O—, —C(═O)—, —OC(═O)—, —C(═O)O—, —NHC(═O)—, or —C(═O)NH—, and
- one of Z51 and Z52 represents a polymerizable group having an ethylenically unsaturated bond, and the other of Z51 and Z52 represents a hydrogen atom,
- in a case where X51 represents —O— and Z51 represents the polymerizable group having an ethylenically unsaturated bond, the polymerizable group having an ethylenically unsaturated bond which is represented by Z51 is a vinylphenyl group, and
- in a case where X52 represents —O— and Z52 represents the polymerizable group having an ethylenically unsaturated bond, the polymerizable group having an ethylenically unsaturated bond which is represented by Z52 is a vinylphenyl group.
A method of producing a compound, comprising:
- reacting a compound represented by Formula (6) with a compound represented by Formula (7) to produce a compound represented by Formula (5),
- in Formula (6), R61 and R62 each independently represent a hydrogen atom, an alkyl group, or an aryl group, and
- R63 represents an alkyl group and R64 represents a hydrogen atom,
- Z71—Y71-E71 (7)
- in Formula (7), E71 represents a group that reacts with a hydroxy group of Formula (6),
- Y71 represents a single bond or a divalent linking group, the divalent linking group is a hydrocarbon group or a group having a structure in which two or more hydrocarbon groups are bonded via a linking group, and the linking group represents —O—, —C(═O)—, —OC(═O)—, —C(═O)O—, —NHC(═O)—, or —C(═O)NH—, and
- Z71 represents a polymerizable group having an ethylenically unsaturated bond,
- in Formula (5), R51 and R52 each independently represent a hydrogen atom, an alkyl group, or an aryl group,
- R53 represents an alkyl group and R54 represents a hydrogen atom,
- X51 and X52 each independently represent —O—, —OC(═O)O—, or —OC(═O)NH—,
- Y51 and Y52 each independently represent a single bond or a divalent linking group, the divalent linking group is a hydrocarbon group or a group having a structure in which two or more hydrocarbon groups are bonded via a linking group, and the linking group represents —O—, —C(═O)—, —OC(═O)—, —C(═O)O—, —NHC(═O)—, or —C(═O)NH—, and
- one of Z51 and Z52 represents a polymerizable group having an ethylenically unsaturated bond, and the other of Z51 and Z52 represents a hydrogen atom,
- in a case where X51 represents —O— and Z51 represents the polymerizable group having an ethylenically unsaturated bond, the polymerizable group having an ethylenically unsaturated bond which is represented by Z51 is a vinylphenyl group, and
- in a case where X52 represents —O— and Z52 represents the polymerizable group having an ethylenically unsaturated bond, the polymerizable group having an ethylenically unsaturated bond which is represented by Z52 is a vinylphenyl group.
Dependencies are inferred from the claim text.