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US 12,655,363 B2Granted
Aqueous dispersions of paraffin inhibitors
AssigneeBASF SE
InventorsFrank Pirrung, Rainer Packe-Wirth, Oscar Lafuente Cerda, Serge Ikink, Jan Donath
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Abstract
Aqueous dispersion of paraffine inhibitors, comprising a continuous aqueous phase comprising water and a water-miscible organic solvent, a dispersed phase comprising at least one paraffin inhibitor component, and at least one anionic surfactant, methods of manufacturing such aqueous dispersions, and the use of such aqueous dispersions as paraffin inhibitor or pour point depressant for crude oil or other hydrocarbon fluids, such as fuel oils or diesel.
Claims12
An aqueous dispersion comprising at least
- (A) a continuous aqueous phase comprising water and a water-miscible organic solvent,
- (B) a dispersed phase comprising at least one paraffin inhibitor component having a melting point of not more than 100° C., wherein the amount of the paraffin inhibitor component is from 10% to 60% by weight relating to the total of all components of the aqueous dispersion, and the paraffin inhibitor component comprises at least
- 30% to 100% by weight-relating to the total of the paraffin inhibitor component-of at least one polymeric, oil-soluble paraffin inhibitor (X),
- 0% to 70% by weight-relating to the total of the paraffin inhibitor component-of a hydrocarbon or a hydrocarbon mixture having a boiling point of at least 100° C., and
- (C) at least one surfactant (S),
- wherein
- the surfactant (S) is anionic and comprises at least one anionic group selected from sulfonate, sulfate, phosphonate or phosphate groups,
- the amount of the surfactants (S) is from 1% to 7% by weight relating to the paraffin inhibitor component, and
- the D50 particle size (volume size distribution) of the dispersed phase, measured by dynamic light scattering is from 50 nm to 500 nm,
- wherein the polymeric, oil-soluble paraffin inhibitor (X) is paraffin inhibitor (X1), wherein
- paraffin inhibitor (X1) comprises, as monomers,
- a-olefins having 10 to 60 carbon atoms, and
- monoethylenically unsaturated monomers comprising carboxylate groups, where some or all of the carboxylate groups have been reacted with aliphatic, cycloaliphatic or aromatic alcohols and/or primary amines, with the proviso that at least 50 mol % of the alcohols or primary amines are linear aliphatic alcohols or linear aliphatic amines having 16 to 32 carbon atoms;
- wherein the aqueous dispersion is stable and fluid when stored at −20° C. for a storage period of at least four weeks.
11 more elements
Dependencies are inferred from the claim text.