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US 12,655,357 B2Granted
Method for producing resins from rubber chips
AssigneeCompagnie Generale Des Etablissements Michelin
InventorsMarc Sutter, Pedro Borges
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Abstract
A method of production of hydrocarbon-containing resins starting from a charge comprising rubber chips comprises at least one pyrolysis step and a resin synthesis step.
Claims13
A method of producing hydrocarbon-containing resins starting from a charge comprising rubber chips, the method comprising:
- (a) pyrolyzing the rubber chips at a temperature between 300 and 900° C. with an increasing temperature ramp to produce a gaseous effluent, a pyrolysis oil and a solid effluent, the pyrolysis oil comprising at least 1.5 wt % C4-C12 olefinic monomers;
- (b) separating the pyrolysis oil into at least one raffinate, an intermediate fraction and an extract, the intermediate fraction comprising 10 to 90 wt % C4-C12 olefinic monomers, 20 to 80 wt % inert compounds, and at most 10 wt % heteroatoms;
- (c) polymerizing the intermediate fraction to produce a first effluent stream;
- (d) stopping the polymerization by contacting the first effluent stream with a stopper compound to produce a polymerized effluent stream;
- (e) separating the polymerized effluent stream into an effluent rich in inert compounds and an effluent rich in resins;
- and
- (f) drying the effluent rich in resins to produce a stream comprising the hydrocarbon-containing resins,
- wherein no inert compounds are externally supplied during the method of production of hydrocarbon-containing resins.
5 more elements
Dependencies are inferred from the claim text.