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US 12,655,329 B2Granted
Hot melt adhesive and uses thereof
AssigneeHenkel AG & Co. KGaA
InventorsDarshak Desai, Yuhong Hu
Life of this patent
Estimating the term…
Abstract
Hot melt adhesive compositions prepared with a mixture of propylene copolymers are disclosed. The hot melt adhesive compositions require little to no oil content while providing high cohesion and excellent adhesion to nonwoven substrates and polymeric films. The hot melt adhesive compositions are particularly suitable for manufacturing absorbent construction articles.
Claims14
A hot melt adhesive comprising:
- (a) about 20 to about 45 wt % of a polymer mixture consisting of:
- (1) a first polypropylene-polyethylene (co) polymer having (i) a viscosity of 3,000 to 8500 cps at 190° C., (ii) a DSC heat of fusion value of less than about 15 J/g measured at 10° C./min heating rate in accordance with ASTM D3418 (iii) a DSC melting peak at about 90-145° C. measured at 10° C./min heating rate in accordance with ASTM 3418;
- and
- (2) a second polypropylene-polyethylene (co) polymer having (i) a melt index of about 15 to about 40 g/10min at 2.16 kg, 190° C., ASTM D1238, (ii) a DSC heat of fusion value of less than about 15 J/g measured at 10° C./min heating rate in accordance with ASTM D3418;
- wherein the ratio of the first polypropylene-polyethylene (co) polymer to the second polypropylene-polyethylene (co) polymer is from about 1.8:1 to about 2.8:1;
- (b) about 30 to about 60 wt % of a tackifier;
- and
- (c) optionally, up to about 30 wt % of a wax or a plasticizer;
- wherein the adhesive has (i) a tan(δ) value of greater than about 30 at 140° C., 10 rad/s and (ii) a melt viscosity of about 2,000 to about 11,000 cps at 150° C., measured in accordance with ASTM 3236.
6 more elements
A hot melt adhesive consisting essentially of:
- (a) about 20 to about 45 wt % of a polymer matrix prepared from a mixture of:
- (1) a first polymer system, wherein the first polymer system has (i) a viscosity of 3,000 to 8500 cps at 190° C., (ii) a DSC heat of fusion value of less than about 15 J/g measured at 10° C./min heating rate in accordance with ASTM D3418, (iii) a DSC melting peak at about 90-145° C. measured at 10° C./min heating rate in accordance with ASTM 3418, and (iv) propylene and ethylene (co)monomers;
- and
- (2) at second polymer system, wherein the second polymer system has (i) a melt index of about 15 to about 40 g/10 min at 2.16 kg, 190° C., ASTM D1238, (ii) a DSC heat of fusion value of less than about 15 J/g measured at 10° C./min heating rate in accordance with ASTM D3418, and (iii) propylene and ethylene (co)monomers;
- wherein the ratio of the first polymer system to the second polymer system ranges from about 1.8:1 to about 2.8:1;
- (b) about 30 to about 60 wt % of a tackifier;
- (c) about 10 to about 30 wt % of a wax or a plasticizer;
- and
- (d) about 0.1 to about 6 wt % of an additive selected from the group consisting of antioxidant, colorant, filler, UV absorber, UV inhibitor, pigment, compatible coating for packaging purpose, and mixtures thereof;
- wherein the adhesive has (i) a tan(δ) value of greater than about 30 at 140° C., 10 rad/s and (ii) a melt viscosity of about 2,000 to about 11,000 cps at 150° C., measured in accordance with ASTM 3236.
7 more elements
Dependencies are inferred from the claim text.