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US 12,655,055 B2Granted
Glass, method for producing a glass, and glass melting apparatus
AssigneeSchott AG
InventorsArmin Vogl, Joerg Hessenkemper, Knut Jakobi, Klaus-Dieter Duch, Andreas Sprenger, Michael Hahn, Klaus-Peter Koenig, Thomas Pfeiffer
Life of this patent
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Abstract
A glass element has, per kg of glass, 50 or fewer inclusions having a size of 2 μm to 10 μm. The glass element can be made of borosilicate glass.
Claims16
A glass element made of borosilicate glass,
- wherein the glass element has, per kg of glass, 50 inclusions or fewer having a size from 2 μm to 10 μm,
- wherein the inclusions comprise gaseous inclusions, solid metallic inclusions, and solid nonmetallic inclusions,
- wherein the glass element has a composition that comprises, in wt %:
- SiO2 76 to 90%;
- B2O3 up to 20%;
- Al2O3 0 to 20%;
- Li2O 0 to 10%;
- Na2O 0 to 10%;
- K2O 0 to 10%;
- MgO 0 to 10%;
- CaO 0 to 10%;
- SrO 0 to 10%;
- and
- BaO 0 to 10%.
11 more elements
A method for producing a glass element made of borosilicate glass comprising the steps:
- i) providing a batch, comprising, in wt %:
- SiO2 60 to 90%;
- B2O3 0 to 20%;
- Al2O3 0 to 20%;
- Li2O 0 to 10%;
- Na2O 0 to 10%;
- K2O 0 to 10%;
- MgO 0 to 10%;
- CaO 0 to 10%;
- SrO 0 to 10%;
- and
- BaO 0 to 10%;
- ii) heating the batch to form a glass melt,
- iii) conditioning the glass melt, and
- iv) cooling the glass melt to provide the glass element, wherein, during step ii) and/or iii):
- a) the glass melt is heated at least in part with an electric resistance heater by subjecting electrodes to a heating current, wherein the heating current is an alternating current with a frequency from 1 kHz and 200 kHz is used;
- b) a contact surface with which the glass melt is in contact comprises 30% or more contact material in the form of melt-cast zirconium oxide material with a proportion of over 70 wt % ZrO2;
- and
- c) from 1% to 50% of a volumetric flow is withdrawn from a bottom material of the glass melt in a bottom region of the glass melt,
- wherein the glass element has, per kg of glass, 50 inclusions or fewer having a size from 2 μm to 10 μm,
- wherein the inclusions comprise gaseous inclusions, solid metallic inclusions, and solid nonmetallic inclusions.
18 more elements
Dependencies are inferred from the claim text.